M-MBonding and Structure of Metal String Complexes Cr(dpa)cl from IR Raman and SERS.pdfVIP

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M-MBonding and Structure of Metal String Complexes Cr(dpa)cl from IR Raman and SERS.pdf

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M-MBonding and Structure of Metal String Complexes Cr(dpa)cl from IR Raman and SERS

Subscriber access provided by SOUTH CHINA NORMAL UNIV The Journal of Physical Chemistry A is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Article Metal#Metal Bonding and Structures of Metal String Complexes Cr 3 (dpa) 4 Cl 2 , Cr 3 (dpa) 4 (NCS) 2 , and [Cr 3 (dpa) 4 Cl 2 ](PF 6 ) from IR, Raman, and Surface-Enhanced Raman Spectra Chung-Jen Hsiao, Szu-Hsueh Lai, I-Chia Chen, Wen-Zhen Wang, and Shie-Ming Peng J. Phys. Chem. A, 2008, 112 (51), 13528-13534 ? DOI: 10.1021/jp8081326 ? Publication Date (Web): 24 November 2008 Downloaded from on December 27, 2008 More About This Article Additional resources and features associated with this article are available within the HTML version: ? Supporting Information ? Access to high resolution figures ? Links to articles and content related to this article ? Copyright permission to reproduce figures and/or text from this article Metal-Metal Bonding and Structures of Metal String Complexes Cr3(dpa)4Cl2, Cr3(dpa)4(NCS)2, and [Cr3(dpa)4Cl2](PF6) from IR, Raman, and Surface-Enhanced Raman Spectra Chung-Jen Hsiao,? Szu-Hsueh Lai,? I-Chia Chen,*,? Wen-Zhen Wang,? and Shie-Ming Peng? Department of Chemistry, National Tsing Hua UniVersity, 101 Kuang Fu Road Section 2, Hsinchu, Taiwan 30013, Republic of China, and Department of Chemistry, National Taiwan UniVersity, Taipei, Taiwan 10617, Republic of China ReceiVed: September 12, 2008; ReVised Manuscript ReceiVed: October 17, 2008 We recorded infrared, Raman, and surface-enhanced Raman scattering (SERS) spectra of metal-string complexes Cr3(dpa)4X2 (dpa ) di(2-pyridyl)amido, X ) Cl, NCS) and [Cr3(dpa)4Cl2](PF6) and dipyridylamine (Hdpa) to determine their vibrational frequencies and to study their structures. For the SERS measurements these complexes were adsorbed on silver nanoparticles in aqueous solution to eliminate the constraints of a crystal lattice. From the results of analysis of the vibrational normal modes we assign the infrared