球磨时间对粉末冶金制备Ti35Nb2.5Sn10HA生物复合材料微观组织的影响.pdfVIP

Trans. Nonferrous Met. Soc. China 22(2012) 604−607 X-ray peak profile analysis of dislocation type, density and crystallite size distribution in cold deformed Pb-Ca-Sn alloys F. ABOUHILOU, A. KHEREDDINE, B. ALILI, D. BRADAI Faculty of Physics, University of Sciences and Technology Houari Boumediene, BP 32 El-Alia, Algiers, Algeria Received 16 June 2011; accepted 9 August 2011 Abstract: The density, nature of the dislocations and distribution of the domain sizes in cold-deformed Pb−Ca−Sn solid solution were determined by X-ray diffraction profile analysis. The dislocation densities are of the order of 1010 cm−2. The strain broadening of diffraction profiles was accounted for by dislocation contrast factor. The coherent domain size was determined by the recently developed PM2K software package. Assuming that the domain size distribution is log-normal, the distribution function (median µ and variance σ) was calculated from the size parameters determined from X-ray diffraction profile analysis. Key words: Pb−Ca−Sn alloy; cold work; X-ray diffraction profile analysis (XRDLPA); PM2K software 1 Introduction During the last decades, the increasing market for maintenance-free batteries promoted the development of the Pb−Ca−Sn alloys. These alloys showed better mechanical and electrochemical properties and were progressively replacing the Pb−Sb alloys for the manufacturing of grids. The different processes of the grid production (gravity casting, continuous casting, rolling expansion and casting expansion) generate a moderate to severe deformation levels in the microstructure [1]. The level of these deformations is the key factor determining the evolution of the morphology and the kinetics of the phase transformations that can o