Solid phase extraction and stir bar Liquid Chromatography Determination of alkylphenol pollutants in water samples.docVIP

 PAGE \* MERGEFORMAT 17 Solid phase extraction and stir bar Liquid Chromatography Determination of alkylphenol pollutants in water samples Of: Lin Fuhua Qiuning Ning Huang Xiaojia * Yuan Dongxing [Abstract] proposed a simple, rapid and sensitive determination of BPA in the environment A (BPA, octylphenol (OP, nonylphenol (NP method. To poly (N-vinyl imidazole - divinylbenzene overall material coated stir bar for the solid phase extraction enrichment of the target, then with high performance liquid chromatography - diode array detector coupled with determination of alkylphenols in water samples pollutants. The effects of extraction time, analytical time, sample matrix pH, ionic strength and other experimental conditions on the extraction efficiency. in the best condition, 3 is the linear range of the target compound 1.0 ~ 200 μg / L, detection limit LOD (S / N = 3 0.13 ~ 0.66 μg / L between the limits of quantification LOQ (S / N = 10 in 0.44 ~ 2.19 μg / L between. in the water and sewage treatment plant on the actual water samples, 3 different target compounds spiked levels of recycling rate of 37.8% ~ 101.1%. The method is simple, fast, efficient, sensitive and so on. [Keywords:] Stir Bar SPE; overall materials; high performance liquid chromatography; bisphenol A; octylphenol; nonylphenol Abstract A method for the determination of bisphenol A, octyphenol, nonylphenol in water samples was developed using stir bar sorptive extraction (SBSE) based on poly (vinylimidazole-divinylbenzene) monolithic material (SBSEM) combined with high performance liquid chromatography with diode array detection. To achieve the optimum extraction performance, several main extraction parameters, including extraction and desorption time, pH value and contents of inorganic salt in the sample matrix, were investigated.Under the optimized experimental conditions, the method showed good linearity and repeatability, low detection limits (S / N = 3) and quantification limits (S