第五章塑料太阳脑谲电池.ppt

这种结构增大了给体－受体界面，使异质结更加分散，减小了激子的扩散距离，更多的激子得以到达界面进行电荷分离，这种异质结被称为体相异质结（bulk heterojunction）。另外，在这种互穿网络中，空穴可以通过供体网络传输到高功函的电极（如ITO、Au），电子通过受体网络传输到低功函的电极（如Al、Mg等），更有利于载流子的传输与收集。1995年，Yu值得MEH－PPV/C60互穿网络结构的太阳电池，电荷收集效率达29％，能量转换效率为2.9％。两指标均较双层或多层膜结构有了大幅度的提高。 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. BHJ 只需要制作单层器件，就可以在活性层内产生D-A 异质结,所以大大简化了器件的制备工艺，克服了多层器件加工过程中上层溶剂对底层聚合物的再溶解腐蚀问题。 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. BHJ太阳能电池的突破受益于Sariciftci 等人发现的共轭聚合物与富勒烯C60之间有效的电子转移现象。在共轭聚合物中光诱导产生的电子，可以在45fs内转移到富勒烯中，电荷分离效率接近100%。 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. polymer solar cells(PSCs) solution processibility processed with spin coating、ink jet printing、screen printing、roll-to-roll production Flexibility low cost eco-friendly light-weight etc. Advantages of PSCs over inorganic solar cells: a b c d Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Pictures of roll-to-roll production with PDTTDABT. (Top) Coating of active layer. (Middle) Coating of PEDOT layer. (Bottom)Lamination of the finished modules and test of single module under a solar simulator. PDTTDABT Large-area, flexible, and printable polymer solar cell demonstrated by Siemens AG, Germany Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Heeger- Low Cost “Plastic”Solar Cells Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. 国际上最热的研究领域 专家表示：有机聚合物太阳能电池效率只要超过10%，就具有商业化应用价值，比无机太阳能电池更有优势。 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. 有机太阳能电池（聚合物和小分子）的发展阶段及最高效率 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. 塑料太阳能电池创造新纪录