酸性偶氮染料还原产物强化偶氮染料生物脱色_张隆.pdfVIP

中国环境科学 2008,28(3) ：237~241 China Environmental Science 酸性偶氮染料还原产物强化偶氮染料生物脱色 * 张 隆,王 竞 ,周集体,李丽华, 吕 红 (大连理工大学环境与生命学院,辽宁 大连 116023) 摘要：考察醌还原菌群利用酸性偶氮染料的生物还原产物对偶氮染料生物脱色的强化作用.结果表明,酸性红 B 等酸性偶氮染料的还原产 物作为氧化还原介体可以强化多种偶氮染料的生物脱色.当酸性红B 还原产物浓度为 0.2mol/L 时,其对活性艳红 KE-3B 最佳脱色 pH 值为 7~11,在 4~40 ℃范围内脱色率随温度上升而提高.根据高效液相色谱-质谱对酸性红 B 还原产物的分析结果,推测起氧化还原介体作用的物 质是 2-氨基-4-磺酸基-1-萘酚. 关键词：醌还原菌群；酸性红 B ；偶氮染料；氧化还原介体；脱色 中图分类号：X172 文献标识码：A 文章编号：1000-6923(2008)03-0237-05 Enhanced biological decolourization of azo dyes by the catalysis of reduced acid azo dyes. ZHANG Long, WANG * Jing , ZHOU Ji-ti, LI Li-hua, LU Hong (School of Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116023, China). China Environmental Science, 2008,28(3)：237~241 Abstract ：The enhanced biodecolorization of azo dyes by quinone-reducing community with reduced acid azo dyes as redox mediator was investigated. Products reduced from acid red B could enhance the biodecolorization of several kinds of azo dyes as redox mediators. When the concentration of reduced acid red B was 0.2mol/L, the optimal pH for biodecolorization conditions of active red KE-3B were determined from 7 to11 and the decolorization rate increased with the increase of the temperature in the range of 4~40 ℃. In conclusion, it was presumed that 2-amino-1-naphthol-4- sulphonate enhanced the biodecolorization of azo dyes as redox mediators from HPLC-MS results of the products reduced from acid red B. Key words ：quinone-reducing community ；acid red B ；azo dyes ；redox mediator ；biodecolorization 9kg 染料,偶氮染料占 世界上每年生产 10 这种生物还原产物能够在后续的好氧过程中完 60%~70%,据估计,每年约有 10%~40% 的染料随 全矿化,不造成二次污染,实现了以废治废, 降低 水排入环境[1].通常采用的偶氮染料的生物处理 了