220t／h水煤浆锅炉烟气脱硝工艺技术.pdf

学兔兔 化 工 进 展 2013年第32卷第4期 CHEMICAL INDUSTRYAND ENGINEERING PROGRESS ·955· 220 t／h水煤浆锅炉烟气脱硝工艺技术 华 炜，凌 俊 (中国石化北京燕山分公司，北京 102500) 摘 要：介绍了中国石化北京燕山分公司针对220 t／h水煤浆锅炉烟气的特点和脱硝的要求，选取了选择性催化 还原(SCR)技术对该锅炉尾部烟气实施脱硝治理。通过对脱硝方案的研究，确定了脱硝的工艺流程和脱硝的有 关工艺参数。SCR反应器操作温度控制在320~370℃范围内，氨与空气的混合体积比约为5：95，SO2转化率 小于1％，SCR反应区压降小于】000Pa，NH3的逃逸率小于3％ 项目通过建设、试运行和相关测试，锅炉的脱 硝效果达到了北京市地方环保规定的标准。该项目对引进国外技术结合国内大型锅炉的特点进行锅炉烟气脱硝 治理有重要意义。 关键词：水煤浆锅炉；烟气脱硝；选择性催化还原法 中图分类号：X 701 文献标志码：A 文章编号：1000—6613(2013)04～0955—04 DoI：10．3969~．issn．1000—6613．2013．04．040 220 t／h CWM—boiler flue gas denirification technology HUA Wef，LINGJu?-／ (Beijing Yanshan Branch Company，SINOPEC，Beijing 102500，China) Abstract：According to the characteristics of 220 t／h coal water mixture．boiler flue gas and the demand of denitrification，Beijing Yanshan Branch Company of SINOPEC has chosen the selected catalytic reduction(SCR)technology for denitrification．The authors determined the process and design parameters by comparing different denitrification methods．The operating temperature of SCR reactor should be controlled in the range of 32O一370℃，the volume ratio of ammonia and air should be about 5：95，S0，conversion ratio should be 1ess than l％ and pressure drop should be less than 1 000 Pa in the SCR reaction zone．At the same time，the concentration of NH in treated flue gas should be less than 3％．After construction，commissioning and testing，the denitrification effect of this project has achieved the standards prescribed by the local env