桥联茂金属催化1-癸烯聚合及其产物结构与性能.pdf

学兔兔 化 工 进 展 ·1088· CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 20 1 5年第 34卷第4期 桥联茂金属催化1．癸烯聚合及其产物结构与性能 江洪波，毋少庚 (华东理工大学石油加工研究所，上海 200237) 摘要：采用桥联茂金属催化体系rac．Et(1一Ind)2ZrCI2／A1( Bu)3／[Me2NHPh] [B(c6F5)4】一催化 l一癸烯聚合，考察了茂 金属浓度、A1／Zr摩尔比、B／Zr摩尔比、温度、反应时间对反应转化率、黏度和摩尔质量的影响。当反应条件为 1．癸烯20mL、甲苯20mL、Zr／烯摩尔比8×10-’、A1／Zr摩尔比80、B／Zr摩尔比1．5、温度80C、反应时间1h时， 转化率达到96．2％。采用¨C NMR和 H NMR表征了产物的结构，优化条件下所得的聚合产物具有高黏度指数 (259)和低分子量分布 (2．088)，可作为理想的润滑油基础油的原料 关键词：催化剂；聚合；优化；桥联茂金属；1-癸烯 中图分类号：TE 626．3，TQ 316．33 3 文献标志码：A 文章编号：1000—6613(2015)04—1088—06 DoI：10．16085~．issn．1000-6613．2015．04．032 Synthesis and characterization of polymers from 1-decene catalyzed by bridged metallocene JIANG Hongbo，WUShaogeng (Research Institute ofPetroleum Processing，East China University ofScience and Technology，Shanghai 200237， China) Abstract： Polymerization of 1-decene catalyzed by bridged metallocene catalyst system ， rac．Et(1一Ind)2ZrCl2／AI(iBu)3／[Me2NHPh] [B(C6F5)4]一，was studied．The effects of the concentration of metallocene catalyst，A1／Zr mole ratio，B／Zr mole ratio，temperature，conversion time，viscosity and molar mass were investigated．The reaction condition was chosen as follows：1一decene 20mL，toluene 20mL，Zr／1一decene mole ratio 8×10_’，A1／Zr mole ratio 80，B／Zr mole ratio 1．5，reaction temperature 80℃，and reaction time l h．The conversion was 96．2％．The product structure was characterized bv ”C NMR and H NMR ． The polymer obtained under optimized condition has