一种水体环境水质COD检测的紫外-可见光谱法研究.doc

一种水体环境水质COD检测的紫外-可见光谱法研究* 汤斌1 魏彪1 吴德操1 毛本将2 米德伶1 任勇1 冯鹏1 余小柳1 1重庆大学光电技术及系统教育部重点实验室，重庆 400044 2四川碧朗科技有限公司，四川绵阳科学城621900 摘要：针对传统水质化学需氧量(COD)检测方法检测周期长、操作复杂和引入二次污染等问题，本文对COD检测及紫外-可见光谱法原理探讨，并对3种不同COD值的邻苯二甲酸氢钾溶液与两批北京石化水样同时进行CODcr和紫外-可见吸收光谱检测，得到5种水样的CODcr值和紫外-可见吸收谱图。实验结果表明：水质的COD参数与其紫外-可见吸光度有明显的相关性：COD值越大，紫外-可见光吸光度越大。故可将直接紫外-可见光谱技术应用于水质COD检测，该方法检测时间短、操作简便、可重复性好且没有二次污染，具有广阔的应用前景。 关键词：石化水样；化学需氧量；紫外-可见吸收光谱；重铬酸钾法 *四川省科技(2012SZ0111) An application research of UV - visible spectroscopy method to water sample COD measuring (Key Laboratory of Optoelectronic Technology and Systems, Ministry of Education, Chongqing University, Chongqing 400044,China) Abstract: Considering the defects of traditional COD measuring methods that they are time-consuming, of complex operation and causing secondary pollution problems, this paper discusses COD measuring and the principle of UV - visible spectroscopy detecting. We first analyses three kinds of Potassium Hydrogen Phthalate Solution with different COD value and two batches of water samples from Beijing Petrochemical using both CODcr measuring and UV-visible spectroscopy detecting, and then obtain CODcr values and UV-visible spectroscopy graphs of those five kinds of water samples. Results show that: COD value of water sample are obviously correlated with its UV - visible absorbance, and greater COD values corresponds to greater UV - visible absorbance. Thus, UV - visible spectroscopy technology can be directly applied on COD measuring of water sample. This method is fast, of convenient operation, greatly repeatable, and also without secondary pollution, having great application prospects. Keywords: water sample of petrochemical; COD; UV - visible spectroscopy; Potassium dichromate method. 1 引言 人类对可持续发展的自然生态规律认识和对自然界过量索取生态环境恶化面越来越多的人口压力Chemical Oxygen Demand)，即化学需氧量，它是评价水体受污染程度的重要指标。 在我国，目前评价水体受污染程度的COD是用化学方法测量水样中需要被氧化的还原性物质的量 (1) (2) 式(1)，是为待分解的有机物与耗氧量的关系式；式(2)，是补充了生成的NH3与氧气反应生产硝酸盐的关系式。 采用重铬酸盐法检测CODcr的关系式