农田灰钙土中有机质和碳酸钙对Zn吸附-解吸行为的影响.pdfVIP

中国环境科学 2015.35(句: 1786-1793 China Environmental Science 农田灰钙土中有机质和碳酸钙对Zn 吸附一解吸行为的影晌 李虎1 ，贺娟 2，刘冲 l ，武文飞 l ，杨超 2，南忠仁 1* (1.兰州大学资源环境学院，甘肃兰州 730000; 2. 宁夏大学资源环境学院，宁夏银川 750021) 摘要:采用序批平衡法，研究了 Zn 在去除有机质及去除碳酸钙前后灰钙土的吸附-解吸行为.结果表明，在试验土壤中吸附量均随着加入 Zn 浓度的增加而增加，且去碳酸钙土对 Zn吸附固定能力明显低于灰钙土，即有机质对灰钙土 Zn 的吸附影响小于碳酸钙，去有机质及去碳酸钙 前后灰钙土对 Zn 的吸附过程不适合用 Langmuir 方程描述，而 Freundlich 方程能够很好地拟合，调整后的决定系数后均大于 0.90，达到极 显著水平(PO.OI);去除有机质和碳酸钙后灰钙土对Zn 的解吸率都升高，且灰钙土去碳酸钙后解吸率略高于去有机质;去除有机质及碳酸钙 前后灰钙土的解吸量均随吸附量的升高而升高，且去碳酸钙土解吸量最大，去有机质土次之，灰钙士最小;土壤有机质和碳酸钙对 Zn 均有较 强的络合吸附效应，能有效降低 Zn 的迁移活性，从而促进吸附，抑制解吸. 关键词: Zn; 灰钙土:吸附-解吸:有机质:碳酸钙 文献标i只码:A 文章编号 1000-6923(2015)06-1786-08 中图分类号:X EfTect of organic matter and calcium carbonate on behaviors of zinc adsorp创on-desorption onlfrom Ningxia farmland 1 2 1 1 2 1 sierozem soils. LI Hu , HE Jing , LIU Chong , WU Wen-fei , YANG Cha0 , NAN Zhong-ren * (1.College of Earth and Environmental Sciences,Lanzhou University, GanSu Lanzhou 730000, China; 2.College of Earth and Environmental Sciences, Ningxia Universi纱， Yinchuan 750021 , China). China Environmental Science, 2015 ,35(6): 1786-1793 Abstract: The laboratory batch experiments were conducted to studied the effect of organic ma忧er and calcium carbonate on adsorption-desorption behaviors of zinc of sierozem soils in Ningxia farmland. The results showed that the adsorption capacity increased with increasing initial zinc concentrations in the sierozem. The adsorption capacity of zinc in soils removed calcium carbonate were lower than that with calcium. Organic matter had weaker effect on adsorption behaviors of zinc in sierozem soils than calcium carbonate. The adsorption process of zinc could be well described by Freundlich equation than Langmuir equation in different organic and carbonate