尾气中氯甲烷深度回收方法的比较-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 1220· PETROCHEMICAL TECHN0LOGY 2011年第40卷第11期 ．／ 0 e 0口0 0 0 0 5-I-业技术l ‘ 也‘ 尾气中氯甲烷深度回收方法的比较 康志鹏，李保军，贺高红，阮雪华，于长福，种道师 (精细化工国家重点实验室 膜科学与技术研究开发中心 大连理工大学 化工学院，辽宁 大连 116024) [摘要]针对有机硅生产排放尾气中氯甲烷含量过高的问题，在工厂原回收工艺流程的基础上分别采用冷凝法、膜分离法和吸收 法对排放尾气中的氯甲烷进行深度回收处理。以有机硅生产产生的氯甲烷质量分数为27．0％的尾气为设计基础，应用UniSim Design模拟软件对3种改造方案进行模拟分析。模拟结果表明，经过3种改造方案处理后排放尾气中氯甲烷质量分数分别降至 6．2％，6．1％，4．3％，经济效益分别增加270，283，237万元／a。比较3种改造方案的经济效益可知，膜分离法工艺可在低投资、低 消耗的前提下获得最高的经济效益增长，更符合工厂处理氯甲烷尾气的实际需要。 [关键词]氯甲烷；尾气回收；冷凝法；膜分离法；吸收法；UniSim Design模拟软件；有机硅 [文章编号]1000—8144(2011)11—1220—05 f中图分类号]TQ 208 [文献标识码]A Comparison of the Recovery Processes for CH3 CI in the Vent Gas Kang Zhipeng，Li Baojbin，He Gaohong，Ruan Xuehua，Yu Changfu，Chong Daoshi (State Key Laboratory of Fine Chemic~s，Research and Development Center of Membrane Science and Technology School of Chemic~Engineering，Dalian University of Technology，Dalian Liaoning 1 16024，China) [Abstract]The recovery processes for CH3 C1 in the vent gas from organosilicon production were studied．Three methods for the CH3 C1 recovery，namely condensation method，membrane separation method and absorption method，were proposed based on the original process．By using UniSim Design simulation software，these three processes were simulated．The results showed that，after being treated through the three designed processes，the mass fraction of CH3 C1 in the vent gas were reduced from 27．0％ to 6．2％ ，6．1％ and 4．3％ respectively，and the benefits increased by 270×10 ，283×10 and 237 x 10 yuan／a，respectively． [Keywords]chloromethane；vent gas recovery；conde