含氮化合物对FCC催化剂的中毒机理及其应对措施.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第4期 PETROCHEMICAL TECHN0L0GY -457· 含氮化合物对FCC催化剂的 中毒机理及其应对措施 沈本贤 ，陈小博 ，王 劲 ，杨朝合 ，山红红 (1．华东理工大学 化工学院，上海 200237； 2．中国石油大学(华东)重质油国家重点实验室，山东 青岛 266580) [摘要]介绍了含氮化合物X~FCC催化剂的中毒作用机理，对酸碱中和理论、竞争吸附理论、诱导效应及空间位阻效应等多 种理论的分析表明，含氮化合物X~FCC催化剂的毒害作用强弱与其质子亲和力、吸附络合能力、分子大小和分子结构，以及 催化剂活性组分的孔结构等密切相关。概述了各种抗氮催化剂和抗氮T艺的研究进展，列举了抑制含氮化合物毒害FCC催化 剂的应对措施，展望了提高FCC装置加工高含氮原料的发展方向。 [关键词]含氮化合物；流化催化裂化；催化剂中毒机理；抗氮 [文章编号]1000—8144(2013)04—0457—06 [中图分类号]TE 624．4 [文献标志码]A Poisoning Mechanisms of FCC Catalysts with Azotic Compounds and Nitrogen—Resistant Measures ShenBenxian ，ChenXiaobo 一，WangJin ，YangChaohe ，ShanHonghong2 (1．School of Chemical Engineering，East China University of Science and Technology，Shanghai 200237，China； 2．StateKeyLaboratory ofHeavyOilProcessing，ChinaUniversityofPetroleum(Huadong)，Qingdao Shandong 266580，China) l Abstract J The poisoning mechanisms of FCC catalysts with azotic compounds，including the acid— alkali neutralization theory，competitive adsorption theory，inductive effect and steric hindering effect，were summarized．The poisoning extent is closely related to proton affinity，adsorption and complexing capability，molecular size and structure of the azotic compounds and pore structure of the catalysts．The measures of improving the nitrogen-resistant performance of the FCC catalysts were reviewed，such as increasing the acid sites，choosing active matrixes，modilying the zeolites and heightening the reaction temperature and the ratio of the catalysts to oil．The processes for treating