NiO微球的微波辅助合成及电荷传导能力优化.pdfVIP

第 31 卷第6 期 无机材料学报 Vo 1. 31 NO.6 2016 年 6 月 Journal of Inorganic Materials Jun. , 2016 Article ID: 1000-324X(2016)06-0667-06 DOI: 1O.15541/jir Optimizing the Charge Transfer Process by Synthesizing NiO Microspheres on Ni Foam through Microwave-assisted Method 2 HAN Dan-Dan , JING Xiao-Yan , XU Peng-Cheng , TAN Ao , CHENGZhen-Yu (1. College ofChernistry and Pharrnaceutical Engineering, Jilin Institute ofChemical Technology, Jilin 132022, China; 2. College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China) Abstract: The porous nickel oxide microsphere on Ni foarn was adopted to optimize the charge transfer process to improve electrochemical perforrnance by a rnicrowave-assisted rnethod. Microstructure and morphologies of the re- sulting materials were investigated by X-ray diffraction, scanning electron microscope , transmission electron rnicro- scope. Results showed that the as-prepared Niû rnicrospheres with nickel sulfate had average diarneter of -2μrn. The ultrathin secondary nanoflakes composed of nanowire building blocks were interconnected with each other forrning a highly open net-structure. Because of enhanced electron transfer capability, charge transfer resistances of the porous microsphere were reduced and the electrochernical perforrnances were irnproved, the charge-discharge rneasurernents tested at a discharge cuπent ofO.5 A1g showed higher rate specific capacitance (455 F/g). T