Determination of the Specific Surface—Solution Adsorption.pptVIP

Contents Purposes and Demands Principle Apparatus and Reagent Procedure Data Records and Processing Questions Attentions Principle The specific-surface that stands for general surface of 1 g solid is an important characteristic parameter of porosity powder substance. It did good job in fields of manufacture such as catalyze, chromatogram, environmental protection and spinning and scientific research. We determine the specific surface of micro-silica gel with the method of methylthionine-chloride solution adsorption, since the tendency of methylthionine chloride to be adsorbed by most of the solid is the largest in dyestuffs which had been found. It presents the monolayer adsorption which is coincident with the Langmuir adsorption isotherm. As stated in monolayer adsorption theory, when the admolecules cover full on the surface of adsorbent, the area of 1g adsorbent seized by admolecule is that the admolecule’s number is multiplied by the area of an adsorbed molecule. the molar mass of methylthionine-chloride( 373.9), Avogadro constant, the mass of silica gel（g） and the mass of methylthionine-chloride when silica gel comes to the saturated adsorption. It is important to select a substance which has the quite large specific surface in the experiment. Methylthionine-chloride has two adsorption peaks in the visible light wavelength of 445nm or 665nm. We Determine the absorbance change in solution by the 722 type of spectrophotometer on the foundation of the equation below Apparatus and Reagent 722-spectrophotometer 1 Conessi-oscillator 1 Volumetric flask(100ml) 8 Iodine measuring flask(100ml) 1 Spheric aspirator 1 Pipette(10ml, 25ml, 50ml) 3 Methylthionine-chloride solution（500×10-3mg/ml） micro-silica gel Procedure 1.?Determination of the specific surface ⑴ Prepare the Methylthionine-chloride solution of 50×10-3mg/ml