形貌可控氮化钛的合成及光解水产氢性能研究.pdfVIP

同时完全复制了前驱物的形貌结构。我们研究了样品中碳含量对光解水产氢的影 响，比较了三种形貌结构的氮化钛在双硫化物缓冲体系中产氢活性，讨论了形貌 与活性的关系，其中核壳结构样品表现出了良好的催化产氢效果。 3、碳纳米管负载氮化钛的合成及其光解水产氢活性研究 通过原位醇热技术，作者将钛的前驱物固载到碳纳米管上, 再将样品在氨气 中氮化，得到碳纳米管上负载氮化钛的样品。由于引入碳纳米管可以有效的分散 样品，提高样品的比表面积；同时由于碳纳米管的高导电性，抑制电子和空穴复 合，可以更有效地提高光催化活性。采用XRD 、FESEM 、DRS 、TEM、BET 等 测试手段，对产物形貌和组成进行了表征，并重点研究了醇热陈化过程对固载的 影响，所合成样品很好的将氮化钛分散固载到碳纳米管上，增大了比表面积，提 高了活性，并且样品在双硫化物缓冲体系中均具有很好的催化产氢结果。 关键词：原位-碳热还原氮化法;光解水;氢气;光催化;醇热法;球状结构;核壳结 构;空壳结构;碳纳米管 Abstract The research of titanium nitride in catalysis and materials exhibits very important value for theory and potential applications. It should be pointed out that titanium nitride can be utilized as the substitution for noble metal Pt in the catalytic hydrogenation owing to its special properties similar to the latter. Thus, metal nitride has become an important semiconductor for the research of catalysis and materials. Nevertheless, such semiconductor materials have not been explored as an excellent functional materials for storage and transfer energy because of the complicated synthesis craft, low surface area, poor micro/nano architectures, and so on. In order to solve the proposed problems in the synthesis and application process, this thesis focused on exploring novel route for fabricating series of titanium nitride with special morphologies and enhanced catalytic performance based on morphology- composition control. The structure-activity relationships for the as-obtained materials have been also investigated. This thesis mainly contains the following three parts: 1. In-situ carbothermal reduction and N2-nitridation strategy to mesoporous titanium nitride spheres with tunable chamber structures