Chemical preparation of open cage fullerene containing metal-毕业论文翻译.docVIP

Chemical preparation of open cage fullerene containing metal Abstract The chemical method is prepared to open the cage containing the metal fullerenes new approach, this paper describes the characteristics of the method, steps, and the latest developments. Keywords: chemical open-cage fullerene containing metal 1 Introduction In recent years, with a special structure and properties of fullerenes and their derivatives in light, electricity, magnetism and other technology applications demonstrate the broad application prospects [1-3]. Since the carbon-cage molecules found at the beginning, people have envisioned using its hollow carbon cages to wrap some metal ions to form metal containing fullerenes (indicated by M @ Cn). This substance has a potential applications, such as the radioactive 60Co implanted in C60 can be used for local treatment of cancer; will be expected to be made of lithium into the carbon-cage high-performance lithium batteries [4]. In fact, this idea is not a fairy tale, to C60, for example, the molecular diameter of 3.6?, And general metal ion diameter is less than 3?, When the positive ions into the carbon cages will cause expansion of the carbon cage [5], and carbon cage with an internal combination of Ionic bond [6], the metal ions into fullerenes is possible. At present, has been found fullerenes containing metal is often obtained by the arc-discharge method. Gillan and other graphite with a mixture of lanthanide metals as electrodes, in an atmosphere of high-pressure inert gas discharge to be soot, and soot using laser desorption mass spectrometry for detection of toluene extract obtained a series of metal containing fullerene peak [7] . This method is the formation of fullerenes in which the package will be of metal, but with two difficult to overcome the shortcomings: 1. Separation difficulties, has been difficult to find a suitable solvent containing the hollow ball ball-ene-ene and the effective separation; 2. production rate is low