Ion-exchange membrane bubbling causes and preventive measures-毕业论文翻译.docVIP

Ion-exchange membrane bubbling causes and preventive measures [Abstract] the core component of ion-exchange membrane production equipment includes active anode and active cathode, selective ion exchange membrane and the Yin and Yang of the end plate (bipolar cell), for a complete exchange membrane electrolyzer units, determine their important factor is the operating life between the anode and cathode expensive selective ion exchange membrane life. membrane bubbling easily in the course of membrane damage is caused by one of the important reasons, should be based on selective ion exchange membrane electrical proper use of chemical properties in order to avoid bubbling, extending its life. [Keywords:] ion-exchange membrane electrolysis bubbling First, the selective ion exchange membrane electrochemical properties 1. The structural condition of perfluorinated ion-exchange membrane Perfluorinated carboxylic acids, Nafion composite membrane for the anode mainly by the acid layer, the carboxylic acid for the cathode layer and enhanced mesh composed of tetrafluoroethylene, zero-pole electric groove from the surface coating a layer of inorganic membrane material, to inhibit membrane surface and increase gas retention membrane surface hydrophilic, film thickness is 250 ~ 350m, thickness of which acid is 35 ~ 90m. for the cathode side of the barrier layer of carboxylic acid with a high positive ion-selective permeability, high and low current efficiency is the key layer of Teflon fabric for the membrane skeleton, in order to improve film strength. 2. The structure of perfluorinated ion-exchange membrane electrochemical properties Body membrane of the membrane and 1 species of active groups, such groups are fixed by the negatively charged ions, such as-SO 3 H.-COOH and a positively charged Na + form of static key role in the field , the active groups in the anode chamber can be Na + salt aqueous solution of Na + exchange, in order to achieve the migrati