在酸性条件下采用高能球磨法制备Cu2O纳米粉末.pdfVIP

第 22 i赞第6 期 元凯材料学报 Vol. 22 , No. 6 2007 年 11 月 JoulnaJ of Inorgan ic. M时erialFJ Nov. , 2007 )!:j配编号 1000-324X(2007)侃-12.5 1降04 在酸性条件下采用高能球磨法制备 CU20 纳米粉末 陈鼎，倪颂，陈振华，陈更莉，陈刚 (湖南大学材料科学与工程学院，长沙 410082) 摘要$ 采用行是tt!穿机在 pH=2 的稀戴眼将浪中时 Ou 粉进行球膺，球腾饥简体制孵球材质均为纯 Ou， tt 料比为 20:1 ，球磨机转速为拥}r!min，通过 X 射线衍射 (XR川、扫描电子显微镜 (SEM) .透射电子恩徽镜 (TEM) 等对球麟产物选行了煮饭. XRD 纺果表明，球磨损后，所加入的纯 Ou 粉末靠在本转化为 OU20 粉和 球腾 70h Ji苦得剑纯的 Cu 0 粉末，粉米粒度为 50~100nm 并对 OU20 纳米粉米的生成机制皮球膳工艺参锹时 2 Ou， o 形成的影响进行了讨论. 关锁词，机械力化学s 纳米 Ou.o: 高能球麟 中朋分类号I TB383 文献标识码， A Preparing CU 0 Nanoparticlel! in Acid Solution Using High-energy 2 BalJ Milling CHEN Ding , NI Song, CHEN Zhen-Hua , CHEN Geng-Li, CHEN Gang (School 01 Material Science and Engineeríng, Hunan Universíty, Changsha 410082， αIÍna) A bstract: The copper powder was baJl-milled in HC1 阳lution (pH据2) by high-energy ball millìng. Both milling balls and contaìncr were made of pure copper. The weíght ratio of Cn balls with ín diameter of 15rmn to the weight of powder w，剧 20:1 ， and all mìlling w嗣 carrìed out at a speed of 300r/皿in. The p旧e copper powder was transformed to CU20 fundmentally a仇er 3h ball milling while the p山e CU20 with the diameter of 5~.lOOnm was ohtained after 70h baJl milling. The as-synthesízed productθW时e characterized by X-ray di岱action (XRD)，配anning e1ectron microsωpe (日EM) and transmission elcctron nucr倒∞pe (TEM). The m时anism of the formation of CU20 and the effect of milling parameters on thefο，rmatìon of CuzO were dí配ussed. Key words: mech翩。chemistry; CU20 nanoparticle: high-energy