工业黄磷中磷及微量杂质含量的测定.pdfVIP

无机盐工业 第 40 卷第4 期 INORGANIC CHEMICAlS INDUSTRY 57 2008 年4 月 工业黄磷中磷及微量杂质含量的测定 何家鸿 (昆明马龙化工有限公司质控部，云南昆明 650117) 摘 要:黄磷产品中除了主含锺磷以外，还含有其他杂质，如:有机杂质、帅、铅、就等。为了解决目前工业黄磷 回家标准中磷含嚣的测定方法巾的有机物的干扰问趟，通过探索，可以采用磷锢酸喽琳意;在法测定黄磷中的磷含 景。该方法是利用?昆合酸来榕解黄磷样品，通过进一步的水解，使黄磷样品中的磷完全转化成正磷酸，根据分析测 定后得到的磷匍酸噎琳的质量求出单质磷的含最。由所获得的分析数据来看，该方法的可靠程度较高，可以应用 于黄磷中磷含量的测定。利用附加的分析方法，还可以同时解决黄磷样品中其他微垦杂质的分析检测工作。 关键询:黄磷产品;磷;微量杂质测定 中图分提号:TQ126.31 文献标识码:A 文章编寄:1∞6 -4990(2ω8)04-ω57 -03 Determination of the contents of phosphorus and trace impurities in the industrial yellow phosphorus He liahong (Depart阳rù ofQωlity Corùrol ,Kunming Ma l.nng Chemical C01叩any， Kunming 650117 ,Chína) Abstract: In addition to the main content of phosphorns ,yellow phosphorus products also contain other impuritie白， such ωorganic impurities ,arsenic ,lead ，自ulfur and 50 on. In order to r自由。，lve the interference of organic matter回 in determiníng 由e phosphorus content based on the current National Stand时，exploratíon disclosed that phosphomolybdic acid quinoline gravimetric method can be applied ín the determinatíon of phosphorus content in the yellow phosphorns. The method uses the mixed acid to dissolve yellow phosphorus sample and through fu此her hydrolysis to let the phosphorus in the sample transform into phosphoric Rcíd completely. Then figure out the mass of quinolíne phosphomolybdate 白。ugh analysís. Finally ,the ele- mental phosphorous content can be calculated according to the mass of quinoline phosphomolybdat日. From the analysis of da- ta obtained ,the reliability of the method is in a high d暗gree and it can be