气液两相滑动弧等离子体处理甲基紫.pdfVIP

中国环境科学 2007，27(6)：786-791 China Environmental Science 气液两相滑动弧等离子体处理甲基紫 刘亚纳 ，严建华 ，李晓东 ，杜长明 ，戴尚莉 ，岑可法 (1．浙江大学热能工程研究所，浙江杭州310027：2 中山大学环境科学与工程系，广东 广州510275) 摘要：采用气液两相滑动弧等离子体降解甲基紫溶液，研究了溶液初始pH值、载气类型、溶液初始浓度对甲基紫降解的影响，并探讨了甲 基紫的降解机理．结果表明，300mg／L的甲基紫溶液，经g次循环降解后(20min)，降解率达99％，COD的去除率达83％．初始溶液的pH值对甲 基紫的降解几乎没有影响．分别以空气、氧气为载气，其降解率差别不大．甲基紫降解率随溶液初始浓度增大而降低，但绝对降解量随溶液初 始浓度增大而增大．从能效比考虑。滑动弧等离子体适合降解高浓度的有机废水．对降解前后的紫外一可见光谱、红外光谱及GC—MS结果分 析表明，甲基紫的共轭结构被破坏，但溶液中仍有少量含苯环的化合物以及酸等小分子化合物存在． 关键词：滑动弧放电；非平衡等离子体；甲基紫；脱色率；气液两相 中图分类号：X703．1 文献标识码：A 文章编号：1000—6923(2007)06—0786—06 Degradation of metbyI violet solution by gas-liquid gliding arc discharge．LIU Ya-na ，YAN Jian—hua ，LI Xiao-dong ， DU Chang-mingz ， DAI Shang-li ，CEN Ke—fa (1．Institute for Thermal Power Engineering，Zhejiang University, Hangzhou 3 10027，China：2．College of Environm ental Science and Engineering，Sun Yat-sen University,Guangzhou 510275，China)．ChinaEnvironmentalScience，2007，27(6)：786~791 Abstract：The influence of initial solution pH value，cartier gas type，and initial mass concentration on the degradation efficiency of methyl violet were investigated using a gas—liquid gliding arc discharge reactor；and the degradation mechanism Was also analyzed．For 300 mg／L methyI violet solution，the degradation efficiency reached 99％，and the 。 removed efficiency of COD Was 83％after quartic circling(20min)degradation．The effect of initial pH value Was not obvious，andthedegradation efficiencyWasalmostthe sflmewith02and airas carriergas respectively．Withincreasingof initial solution concentration，the degradation efficiency decreased and the absolute degradation quantity increased． Taking into account the ratio ofenergy and efficiency,gliding arc discharge Was suitable to degrade hi曲concentration organic wastewater．UV-vis spectroscopy,FTIR and GC-MS of the products showed that the conj