具有均一尺寸球形碳气凝胶的制备和其储能研究.pdf

Hans Journal of Nanotechnology 纳米技术, 2017, 7(1), 1-10 Published Online February 2017 in Hans. /journal/nat /10.12677/nat.2017.71001 Preparation and Stored Energy Performance of Spherical Carbon Aerogels with Uniform Size * # Yalei Deng , Yong Deng, Yongwang Ma, Jie Wang, Yajun Ji Department of Chemistry, College of Science, University of Shanghai for Science and Technology, Shanghai th th th Received: Jan. 27 , 2017; accepted: Feb. 12 , 2017; published: Feb. 15 , 2017 Abstract Different pH values of sodium carbonate solution were used as catalyst for condensation of resorci- nol and formaldehyde to obtain organic gels. After high temperature carbonization, the organic gels were transformed to carbon aerogels. The obtained materials were characterized by SEM, TEM and N2 adsorption desorption test. In addition, the electrochemical performance, such as cyclic voltam- metry and galvanostatic charging and discharging tests, was also conducted. SEM results show that the morphologies of carbon aerogels exhibit the transformation from sole macrosomia to sphere and eventually to sole macrosomia via elevating the pH value of precursor solution. It can be noted that different forms of carbon aerogels can be obtained via regulating the pH of the precursor solu- tion. Especially, when the pH of sodium carbonate solution is 10.49, the prepared carbon aerogels exhibit spherical structure with uniform particle size. N2 adsorption and desorption tests show that the specific surface area of the spherical carbon can up to 526.1 m2/g. Cyclic voltammetry and gal- vanostatic charging and discharging tests show that the uniformly spherical carbon aerogels