中间相沥青纤维的预氧化和应力应变行为研究.PDF

第32卷摇 第3期 新摇 型摇 炭摇 材摇 料 Vol.32摇 No.3 摇 2017年6月 NEW CARBON MATERIALS Jun. 2017 摇 文章编号:摇 1007鄄8827(2017)03鄄0284鄄05 中间相沥青纤维的预氧化和应力应变行为研究 孙祝林,摇 奚立华,摇 李摇 红,摇 曾凡龙,摇 吕永根 (东华大学 材料科学与工程学院,上海 201620) 摘摇 要:摇 采用傅里叶红外和动态热机械分析仪对中间相沥青纤维预氧化过程进行研究。 结果表明,纤维中的应力在175 益 前迅速降低;在氧化过程中,脱氢反应显著,同时羟基减少;到250 益以上醚键增加,大量的交联反应发生,应力增大,在恒定应 力下纤维伸长速率减缓;270 益以上时纤维稳定化程度较高,产生收缩;整个氧化过程中含氧官能团的增加并不显著。 结合纤 维在垂直和水平两种状态下的受力分析认为,连续预氧化时,沥青纤维自身重力不容忽略,沥青预氧化炉宜采用立式设计。 关键词:摇 中间相沥青纤维;氧化;交联 + 中图分类号:摇 TQ342 .74 文献标识码:摇 A 收稿日期:2017鄄02鄄26;摇 修回日期:2017鄄05鄄10 基金项目:国家自然科学基金. 通讯作者:吕永根,研究员.E鄄mail:yglu@ 作者简介:孙祝林,硕士研究生.E鄄mail:ycsunzhulin@163.com Fourier transform infrared and dynamic thermomechanical analyses of mesophase pitch fibers during oxidative stabilization SUN Zhu鄄lin,摇 XI Li鄄hua,摇 LI Hong,摇 ZENG Fan鄄long,摇 LU Yong鄄gen (College of Material Science and engineering,Donghua University,Shanghai 201620,China ) Abstract:摇 The stress in and elongation of mesophase pitch fibers during oxidative stabilization were investigated by a dynamic thermo鄄mechanical analyzer under a fixed elongation and strainload,respectively. Their functional groups at different temperatures were characterizedby Fourier transformed infrared spectroscopy. Resultsindicated that when the temperature was below 175 益,a distinct decrease in the stress in the fibers and the number of hydroxyl groups was found,accompanied by dehydrogenation reac鄄 tions. When the temperature wasincreased above250 益,the number of ether bonds and the stress increased,and elongation de鄄 creased due to cross鄄linking reactions. When the temperature was increased further,above 270 益,the fibers began to shrink be鄄 cause oftheincreaseintheextentofstabilization.