氧化-还原引发无皂硅丙乳液聚合研究.pdfVIP

钎 彘巍 全国中文核心期刊 氧化一还原引发无皂硅丙乳液聚合研究 于双武 ，张宝莲 ，魏冬青 ，刘忠义 (1．天津永盛岩土有限公司，天津 30038l； 2．天津城市建设学院材料科学与工程系，天津 300384) 摘要：采用种子乳液法，以反应性表面活化剂十 一烯酸钠为表面活性单体，过硫酸钾／亚硫酸氢钠为氧化还原引发体系，进行丙 烯酸酯无皂乳液聚合以及肯机硅改性丙烯酸酯无皂乳液聚合研究。详细考察了反应温度、十一烯酸钠用量以及有机硅加入与否对乳 液聚合和乳液性能的影响。研究结果表明，当卜 烯酸钠用量为3％、反应温度为7O℃时，丙烯酸酯乳液有很好的聚合稳定性和贮存 稳定性。有机硅改性丙烯酸酯乳液相对较难合成，但在氧化还原条件下，可以得到稳定的无皂硅丙乳液。透射电镜表明，有机硅先加 法得到的乳胶粒 为均匀的球形核壳结构，而有机辞后加法得到的乳胶粒子形状不规则。无皂乳液比相应的有皂乳液耐水性好。 关键词：无皂乳液；有机硅；表面活性 体；十一烯酸钠 中图分类号：TQ331．4 文献标识码：A 文章编号：1001—702X(2008)02—0053—04 Study on polymerization of nonsoap polysiloxane-acrylate emulsion by redox initiation YU Shuangwu ，ZHANG Baolicm Dongqinf，LIU Zhonyi (1．The Yongsheng Geotechnical Engineering Co．Ltd．，Tianjin 300381，China： 2．Department of Materials Science and Engineering，Tianjin Instiiute of Urban Construction，Tianjin 300384，China) Abstract：Study has been made on polymerization of nonsoap acrylate emulsion and organosiloxane modified nonsoap acrylate emulsion using sodium undecylenate(NaUA)as surface active monomer and K2s2O8／NaHSO3 as redox initiation system adopting seed emulsion method．The effect of polymerization conditions including reaction temperature，the amount of NaUA and the effect of presence of organosiloxane on polymerization and property of the emulsion was studied systematically．The study result indicates that amTlate emulsion is veDstable during the emulsion polymerization and storage when the addition of sodium undecylenate is 3％ and reaction temperature is 70℃．The organosiloxane modified nonsoap acrylate emulsion is relatively difficult to synthesis．Yet a stable nonsoap polysiloxane—acrylate emulsion can be obtaine