Characterization of the ageing of HTPB bonded （描述的老龄化HTPB保税）.pdf

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Characterization of the ageing of HTPB bonded （描述的老龄化HTPB保税）.pdf

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Characterization of the ageing of HTPB bonded （描述的老龄化HTPB保税）

Characterization of the ageing of HTPB bonded HMX based insensitive high explosive charge by Heat Flow Microcalorimetry (HFC), Chemiluminescence, Gap test and Dynamic Mechanical Analysis (DMA) Dr. Manfred A. Bohn Fraunhofer-Institut fuer Chemische Technologie, ICT Presented on NDIA 2009 Insensitive Munitions and Energetic Materials Technology Symposium May 11 to 14, 2009, Ventana Canyon Tucson, Arizona, USA ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 2009 Bohn / Titel 1 Content Composition of high explosive charge (HEC) HTPB-HMX Objectives Basic stability data Time-temperature (ageing) program for HEC Sensitiveness by gap-test Glass transition temperature determined by torsion DMA Heat generation rate between 120°C and 150°C Chemiluminescence in air between 100°C and 140°C Summary and conclusions ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 2009 Bohn 2 What is HEC of type KS 32 KS32 is a polymer bonded high explosive charge (HEC), manufactured by EADS-TDW, Schrobenhausen, Bayern, Germany (now part of MBDA) Typical composition Energetic material HMX 85.0 mass-% Binder HTPB cured with IPDI 13.7 mass-% Plasticizer DOA 1.0 mass-% Antioxidant