无机化学第四版下册16章习题答案（Inorganic chemistry Fourth Edition Volume 16 chapter exercises answer）.docVIP

无机化学第四版下册16章习题答案（Inorganic chemistry Fourth Edition Volume 16 chapter exercises answer） The sixteenth chapter is nitrogen, phosphorus and arsenic 16-1 please answer the following questions about the nature of nitrogen: (1) why is the bond energy (167kJ.mol-1) of the N-N bond smaller than that of the P-P bond (201 kJ.mol-1)? N = N bond (942 kJ.mol-1) than the P = P bond (481 kJ.mol-1) large? (2) why can nt nitrogen form five halides? (3) why is the first ionization energy of N2 smaller than that of N atom? 1. Solution: (1) N, because its inner electron is few and the atom radius is small, the valence electron layer has no D orbit which can be used as bonding. The bonds of N-N single bonds can be abnormally smaller than the third cycle P-P bond, and N tends to form P-P bonds (including delocalized bonds), so the bonds of N=N and NN are larger than other elements. (2) the valence electron layer does not have a d orbital that can be used as a bond. N can only form 4 covalent bonds, i.e., the coordination number of N is not more than 4. (3) the P orbits of valence electrons in N atoms are just half filled. 16-2 please answer the following questions: (1) how do I get rid of the moisture in a small amount of NH3 and NH3 in N2? (2) how to remove trace amounts of NO from NO2 and N2O in NO? 2 solution: (1) pass the gas through the dilute H C l solution; pass the alkali lime (2) by NaOH solution; 16-3 discuss the strength of the bond energy between H2O, NH3 and proton in the case of proton transfer between NH3 and H2O; why acetic acid is a weak acid in water, but it is strong in liquid ammonia solvent 3. Solution: NH3, +H2O=NH4+, +OH-; Therefore, the bonding ability between NH3 and proton is stronger than that of H2O and proton. Because of this, the binding ability of acetic acid to water is weaker than that of acetic acid and ammonia. This is known as the solvent levelling effect. 16-4 order the following substances in the order of alkaline reduction and give an explanation.