第五章 热力学基础（The fifth chapter is the basis of thermodynamics）.docVIP

第五章 热力学基础（The fifth chapter is the basis of thermodynamics） The fifth chapter based on Thermodynamics 5-1, the first law of thermodynamics and its application A, can Can all objects in the random motion of molecular kinetic energy (+ molecular vibrational energy, interaction energy). internal energy Real gas: (in 2 independent) Ideal gas: Note: the value function of the state, by the () (decision only 2 independent variables), as a state function, the increment is only related to the whole story two state, and has nothing to do with the process. The ideal gas temperature is the single value increasing function. The equivalent of two, heat and work Experimental results show: once the Joule heat transfer function and the system at the same temperature, the heat transfer and the work done there is always a certain ratio, i.e. 1 calories =4.18 joule of work Therefore, heat and work is equivalent to. By mechanical know. The system work is the transfer of energy to the power system, since the heat transfer and equivalent to the heat transfer system also means to transmit energy to the system. Conclusion: the work of two ways of energy transfer Conduct heat Note: Although there is a work of heat transfer and equivalent, but the essence is different. The difference between work done by: object macro displacement. Function is to convert the mechanical motion system and irregular movement between molecules. In order to change the internal energy. Heat transfer through intermolecular interactions to complete. Function is to convert the external molecular random thermal motion and system between the rules of thermal motion of molecules. To change the internal energy. Three, the first law of thermodynamics Under normal circumstances, when the system state changes, the power and heat transfer are often exist at the same time. A system for heat transfer to the outside world, so that the system can, at the same time. To the outside world and the power system, then use mathematical