绿麦隆在水溶液中光降解动力学研究-环境科学学报.PDFVIP

19 1 Vol. 19, No. 1 1999 1 ACTA SCIENT IAE CIRCUMSTANT IAE Jan. , 1999 * * * 周祖飞 刘维屏 ( , 310027) , . , , , 23 10- 2 m in- 1; - - Cl CO NO ; GC/ MS , ( 3 4) 2 3 , . ; ; . Photolytic kinetics of chloritoluron in aqueous solution ZHOU Zufei, IU Weiping ( Department of Chemistry, Zhejiang University, Hangzhou 310027) Abstract The photolysis of chlorotoluron [ N! ( 3chloro 4methylphenyl) N, N dimethylureal] was investigated under irradiation of variouswavelength in aqueous solution.The factors that influence the photolysis were also investigated. The degradation process follows a pseudofirstorder kinetic under ultra - 2 - 1 violet light, and the rate constant was determined to be 23 10 min . The herbicide w as mineralized - - to CO , Cl and NO after longterm irradiation. Several photolysis intermediates were identified using 2 3 GC/ MS technique, and 3chloro4methylphenyl isocyanide was recognized as a major reaction intermedi ate. A mechanism of the processw as supposed. Keywords chlorotoluron, photolysis, mineralization. 1 [ N, N N! ( 3 4) ] , , , . [ 1] , 70 . , . [ 2, 3] , . 2 21 (96%) ; * ( * * 1 : 69 ; HP C . 22 ( , 1) ; Spectra Physics , Spectra 100 SP4270 ; Finnigan MAT SSQ7000 ; 751G ( ) ; T G 168( ) ; ZFQ81A ( ) . 23 231 40 cm , 3 1 , Fig. 1 Photolysis reactor