十八烷基超支化分子的结构表征与破乳性能.pdfVIP

第l9卷第l期 化 学 研 究 Vo1．19 No．1 2008年3月 CHEMlCAI RESEARCH Mar．2o08 十八烷基超支化分子的结构表征与破乳性能 张姝妍 ，葛腾杰 ，李翠勤 ，王 俊 (1．大庆石油学院化学化 I：学院，黑龙汀大庆 163318；2．大庆7 化公rd研究院 精细化 I：室，熙龙江 大庆163714) 摘 要：以甲醇为溶剂，用十八胺、丙烯酸甲酯和乙二-二胺为原料，通过迈克尔加成反应和酰胺化缩合反应，制备了 1．0 G超支化分子；通过红外光谱、核磁共振于段对合成产- 的结构进行了表征，f1．考察了十八烷基超支化分子 对O／W型原油模拟乳液的破乳性能，并与传统的线性破乳剂SP一169进行了对比．结果表明：在温度为50℃、添 加量为20 mg／L、破乳时问为120 min的条件下，其脱水率达到了．76．2％，脱出水中的含油量为41．9 mg／L；而破 乳剂SP．169在相同的条件下的脱水率为61．5％，脱出水中的含油量为52．4 mg／L． 关键词：超支化分子； H NMR；破乳剂；模拟乳液 中图分类号：0 633．22 文献标识码：A 文章编号：1008一lOll(2008)0l一0080—03 Characterization and Demulsification Property of Octadecyl Hyperbranched Molecule ZHANG Shu·yan。，GE Teng·jie ，LI Cui·qin‘，WANG Jun‘ (1．College of Chemistry and Chemical Engineering，Daqing Petroleum Institute，Daqing 1 633 1 8，Heilongfiang,China； 2． M Chemical Laboratory,Research Institute of Daqing Petrochemical Company，Daqing 1 637 1 4，Heilongiiang，China) Abstract：The 1．0 G hyperbranched molecule was synthesized with methanol as solvent by means of Michael addition and amidation condensation reaction with octadecy1．amine acrylate and ethylenedia— mine as raw materials．The octadecyl hyperbranched molecules were characterized by IR and。H NMR。 and the demulsification for the simulated crude O／W emulsion was studied and compared to the tradi— tional demulsifier SP一1 69．The results show that when the concentration of octadecyl hyperbranched molecule 1．0 G is 20 mg／L the temperature is 50℃ and the time is 1 20 min the dehydration ratio is 76．2％．and the content of the oil in the separated water iS 41．9 mg／L while the data of SP一169 are 61．5％ and 52．4 mg／L respectively at same conditions．