spectroscopic studies of distorted structure systems in the vibron model application to porphyrin and its isotopomers扭曲的结构系统的光谱研究卟啉及其isotopomers vibron模型应用程序.pdfVIP

Hindawi Publishing Corporation International Journal of Spectroscopy Volume 2011, Article ID 452626, 5 pages doi:10.1155/2011/452626 Research Article Spectroscopic Studies of Distorted Structure Systems in the Vibron Model: Application to Porphyrin and Its Isotopomers Srinivasa Rao Karumuri,1 Vijayasakhar Jallaparthi,2 and Sreeram Venigalla3 1 Department of Electronics and Instrumentation Engineering, Lakireddy Bali Reddy College of Engineering, Krishna District, Mylavaram 523 230, India 2 Department of Mathematics, GITAM University, Hyderabad Campus, Hydrabad 502329, India 3 Department of Chemistry, P.G. Centre, P.B. Siddhartha College of Arts Sciences, Vijayawada 520010, India Correspondence should be addressed to Srinivasa Rao Karumuri, srinivasakarumuri@ Received 7 July 2011; Accepted 13 August 2011 Academic Editor: Veronica Vaida Copyright © 2011 Srinivasa Rao Karumuri et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. We have introduced an algebraic technique to biomolecules (porphyrins) family to determine the vibrational spectra. We present an algebraic model of vibrations of polyatomic biomolecules, as an example, the vibrational analysis of stretching modes of nickel octaetheylporphyrin (Ni(OEP)) and its isotopomers. The algebraic technique obtained the results are compared with experimental data; the results are showing good accuracy. Some reassignments of energy levels that predict location of energy states not yet observed. 1. Introduction entanglement of vibrations in small molecules by employing