hpf法脱硫（Desulfurization by HPF process）.docVIP

下载本文档

19
0
约1.58万字
约 19页
2017-09-05 发布于河南
举报
版权申诉

hpf法脱硫（Desulfurization by HPF process）.doc

1、本文档共19页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

hpf法脱硫（Desulfurization by HPF process）

hpf法脱硫（Desulfurization by HPF process） HPF HPFHPF HPF desulfurization Desulfurization desulfurization Desulfurization HPF desulfurization belongs to liquid phase catalytic oxidation desulfurization catalyst regeneration, HPF in the whole process are in desulfurization and Catalysis is the use of coke oven gas in ammonia absorber, HPF wet oxidation desulfurization catalyst, H2S in gas and other acidic component into the liquid phase and gas phase reaction by ammonia, converted to ammonium thiochloride acid ammonium salt, The oxidation of oxygen in the air into elemental sulfur. HPF process choose to use HPF (cobalt iron quinone complex) Combined type catalyst, the desulfurization efficiency of coke oven gas to reach about 99%. One one by one A, ,, HPF HPFHPF The basic reaction of HPF desulfurization The basic basic reaction for desulfurization desulfurization. The basic method of desulfurization reaction 1. desulfurization reaction NH3+H2O In the H2O NH3. NH3 - H2O +H2S In the NH4HS+H2O NH3 - H2O +HCN In the NH4CN+H2O NH3 H2O in +CO2 NH4HCO3 NH3 H2O in +NH4HCO3 (NH4) 2CO3+H2O NH3 H2O +NH4HS+ (x+1) in Sx (NH4) 2Sx+H2O 2NH4HS+ (NH4) 2CO3+2 (x-1) S In 2 (NH4) 2Sx+CO2+H2O NH rate Exergy in +NH4HCO3 NH4HOO-+H2O NH4HS+NH4HCO3+ (x-1) S In the (NH4) 2Sx+CO2+H2O NH4CN+ (NH4) 2Sx In the NH4CNS+ (NH4) 2S (x-1) (NH4) 2S (x-1+S) In the (NH4) 2Sx 2. regeneration reaction NH4HS+1/2O2, S: +NH4OH (NH4) 2Sx+1/2O2+H2O - Sx +2NH4OH NH4CNS: In the H2N-CS-NH2 in the H2N-CHS=NH H2N-CS-NH2+1/2O2 to H2N-CO-NH2=S: H2N-CO-NH2+2H2O In the (NH4) 2CO32 in the The 3. side reaction exergy NH4OH+CO2 2NH4HS+2O2, (NH4) 2S2O3+H2O 2 (NH4), 2S2O3+O2 (NH4) 2SO4+2S: HPF catalyst desulfurization by hydroquinone (H), PDS (Gu six bicyclic phthalocyanine ammonium sulfonate), ferrous sulfate (F) aqueous solution which is composed of small amounts of ADA, manganese sulfate and salicylic acid catalyst,. The catalytic mechanism of HPF desulfurization catalyst is still in further research, the components in desulfu