生物降解聚合物论文：PBSPA6IcoT交换反应其产物研究.docVIP

生物降解聚合物论文：PBS-PA6IcoT交换反应及其产物研究 【中文摘要】可降解高分子材料近年来备受关注,但大部分聚酯可降解高分子材料存在热性能、力学性能较差的缺点。而聚酰胺则由于含有酰胺键(-CONH-),以及分子链间氢键的存在,具有较好的热性能和力学性能,但聚酰胺难以降解。综合上述两类聚合物的特点,本文拟以高分子量的脂肪族聚酯和半芳香族聚酰胺为原料,经由酯-酰胺交换反应制备高分子量的聚酯酰胺。首先,聚丁二酸丁二醇酯(PBS)和无定形尼龙聚间(对)苯二甲酰己二胺(PA6IcoT)在卧式反应釜中进行熔融反应共混,利用溶解度实验、FT-IR和13C-NMR对交换反应的机理和生成的共聚物的结构进行了表征,并利用扫描电镜研究了交换反应对共混物相形态的影响。结果表明,以对甲苯磺酸(TsOH)为催化剂时,PBS和PA6IcoT之间可发生交换反应。随着反应程度的增大,共聚物的无规度增大,分子量分布变宽。交换反应生成的共聚物可起到相容剂的作用,改善了共混物中两相的相容性,分散相颗粒尺寸明显变小。其次,系统研究了PBS和PA6IcoT熔融共混物的等温和非等温结晶动力学,晶体形态和晶体结构。结果表明,PA6IcoT抑制PBS的结晶,导致结晶活化能增大,结晶速率和结晶度减小。交换反应破坏了产物链段的规整性,更加剧了这一效应。随着反应程度增大,共混物结晶形态发生较大变化,球晶尺寸逐渐减小,界面变得越来越模糊；晶体结构变化较小,但是反应共混物的衍射峰位置出现漂移。最后,探讨了共混物的化学结构和凝聚态结构对共混物热性能、力学性能和降解性能的影响。研究结果表明,由于体系相容性得到改善,两者的玻璃化温度逐渐向中间靠拢。交换反应生成的共聚物链段中含有刚性基团,使得共混物的热分解性能显著提高。PBS和PA6IcoT物理共混时,由于相容性差力学性能下降。随着交换反应程度的增加,PA6IcoT的链段逐渐进入PBS的链段中,产物的拉伸强度、拉伸模量和冲击强度均高于PBS。另外,随反应程度提高,共混物结晶度减小,无规度增加,有利于其生物降解。这样在提高热性能和力学性能的同时,可以保持其可生物降解性。 【英文摘要】In recent years, many researchers are focusing on the environmentally friendly materials, especially on the biodegradable polymers. Most of the biodegradable polymers are polyesters, which have poor thermal properties and mechanical properties. Therefore, their practical applications are limited. On the other hand, the polyamide chains contain amide bond (-CONH-). Because of the existence of hydrogen bonds between molecular chains, they have good thermal and mechanical properties. However, they are not biodegradable. To combine the advantage of two polymers, high molecular weight poly(ester amide)s are prepared by ester-amide exchange reaction between aliphatic polyester and semi-aromatic polyamide.Firstly, amorphous nylon PA6IcoT and poly(butylene succinate) (PBS) are blended in the horizontal reactor under melting conditions. The mechanism of exchange reaction and structure of copolymers are analyzed by solubility experiment, FT-IR and 13C-NMR. Scanning electron microscope (SEM) is used to analyze the influence of exchange reaction on phase morphology. The results show that ester