第四章 配合物（Fourth chapter complexes）.docVIP

第四章 配合物（Fourth chapter complexes） Ninth chapter complexes 9-1: distinguishes the following concepts (a) ligands and complexes, (b) outer orbital complexes and inner orbital complexes, (c) high spin complexes and low spin complexes, (d) strong field ligand and weak field ligand, (E) geometrical isomerism and optical isomerism, (f) reactive complexes and inert complexes, (g) generating constants and generating constants step by step, (H) chelation effect and reverse effect. Answer: Answer: (a) coordination entities are molecules or ions associated with central atoms or ions, called ligands, or ligands; the chemical species (ligands) that give ligand and acceptor are complexes. More broadly, the adduct of Lewis acid with Lewis base. (b) starting from the complex valence bond theory, where the coordination atoms of a solitary electronic filling in the center of atoms or ions from the outer layer of the D hybrid orbital hybrid orbitals, the complexes formed coordination bond is the outer orbital complexes. Instead, it fills the hybrid orbital, which is the inner orbital (n-1) d orbital, the inner orbital complex. (c) starting from the crystal field theory of complexes, due to the relative size of P and delta 0, which combined with electronic material in may have two different array configuration, which contains complex single electron number called high spin complexes, there is no single electron or containing complexes of single electron number less called low spin complexes. (d) when ligand is coordinated with central metal, the ligand ligand field is strong because of the different splitting energy produced by the ligand The following order: I-Br-Cl-F-OH-C2O42-H2OSCN-NH3enSO32-phenNO2-CN, CO. The ligand at the front of the sequence (generally bounded by H2O) is called a weak field ligand, and the ligand at the rear of the sequence (generally bounded by NH3) is called a strong field ligand. (E) isomers of complexes. The isomerism of the ligand around the central atom d