水冷铜坩埚一步铝热法制取高纯钒铝合金-钢铁钒钛.PDFVIP

第34卷第6期 钢摇 铁摇 钒摇 钛 Vol.34,No.6 2013年12月 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 IRON STEEL VANADIUM TITANIUM 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 摇 December2013 水冷铜坩埚一步铝热法制取高纯钒铝合金 1 2 彭予民 ,王摇 恒 (1.宝钢集团有限公司中央研究院,上海200940;2.北京科技大学,北京 100083) 摘摇 要:为了实现低成本制备高纯度钒铝合金的目的,探讨了应用水冷铜坩埚采用一步铝热法制取高纯钒铝合金的 可行性。 通过数轮试验,在原料准备、生产工艺、反应状况以及制备的铝钒合金成分等方面,与采用常规耐火材料炉 一步铝热法制取钒铝合金方法进行比较,结果表明:水冷铜坩埚一步铝热法具有钒元素收得率高,反应稳定性好,制 备的钒铝合金混入杂质含量低等特点,基本满足低成本制备高纯度钒铝合金的要求,并分析了产生上述结果的原因。 关键词:高纯钒铝合金;一步铝热法;水冷铜坩埚;收得率 中图分类号:TF841郾3,TG146郾4摇 摇 文献标志码:A摇 摇 文章编号:1004-7638(2013)06-0025-04 DOI:10.7513/ j.issn.1004-7638.2013.06.006 “One Step冶 Aluminothermic Reduction Process for Preparation of High鄄purity Vanadium鄄aluminium Master Alloy with Water鄄cooled Copper Crucible 1 2 Peng Yumin ,Wang Heng (1. Central Research Institute,Baosteel Group Corporation,Shanghai200940,China;2.University of Science and Tech鄄 nology Beijing,Beijing 100083,China) Abstract:In order to achieve the goal of lowcost production of high鄄purity V鄄Al master alloy,the feasi鄄 bility of employingwater鄄cooledcoppercrucibletopreparethealloyby “onestep冶 aluminothermicreduc鄄 tion process is probed into. After several rounds of experiments,compared with the traditional refractory furnace in raw material preparation,production process,reaction and chemical compositions of the alloy produced,thewater鄄cooledcoppercruciblecanrealizelowerimpuritycontentinalloy,higheryieldofva鄄 nadium and more stable reaction. It can basically meet the requirement of lowcost production. Further鄄 more,the reasonsfor those results are discussed in detail. Key words:high鄄purity V鄄Al