塑料改性用金红石型TiO2的一步法合成及表征-IngentaConnect.PDF

· 391 · 硅 酸 盐 学 报 2011 年 第39 卷第3 期 硅 酸 盐 学 报 Vol. 39 ，No. 3 2 0 1 1 年 3 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY March ，2011 塑料改性用金红石型TiO2 的一步法合成及表征 张国永，周 箭，申乾宏，杨 辉 (浙江大学材料科学与工程系，杭州 310027) 摘 要：以钛酸四正丁酯、硝酸、乙烯基三乙氧基硅烷为原料，利用沉淀法在低温条件下一步合成出塑料改性用金红石型二氧化钛粉体。通过X 射 线衍射、Fourier 变换红外光谱、X 射线光电子能谱、透射电镜等手段对改性粒子的微观结构进行了表征。结果表明：改性剂硅烷与单颗粒TiO2 粒子 表面以Ti—O—Si 键化学键合，改性后的TiO2 与水的接触角达144°，能稳定分散于二甲苯中，可与高密度聚乙烯均匀混炼。 关键词：金红石；二氧化钛；低温；硅烷；表面改性；疏水；分散性 中图分类号：O65 ；TQ31 文献标志码：A 文章编号：0454–5648(2011)03–0391–06 One-Step Synthesis and Characterization of Titanium Dioxide Powder for Plastic Modification ZHANG Guoyong ，ZHOU Jian ，SHEN Qianhong ，YANG Hui (Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China) Abstract: A surface-modified titanium dioxide powder used for plastic modification was synthesized by one-step precipitating method at a low temperature using tetrabutyl titanate, nitric acid and vinyltriethoxysilane as raw materials. Microstructure of the composites were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and transmission electron microscope. The results indicate that the silane is grafted to the surface of single TiO2 particle by Ti—O—Si bond. The contact angle of the modified TiO with water is 144 °, and the TiO particles can stably distribute in xylene and homoge- 2 2 neously mix with the high density polyethylene. Key words: rutile; titanium dioxide; low temperature; silane; surface modification; hydrophobic; dispersity