两种氢氧化铁胶体纯化新方法-大学化学.pdfVIP

大学化学(Daxue Huaxue) 46 Univ. Chem. 2017, 32 (9), 46－51 September ∙化学实验∙ doi: 10.3866/PKU.DXHX201703029 两种氢氧化铁胶体纯化新方法 * 关瀚昌 段昌林 沈腊珍 曾麟翔 (大同大学化学与环境工程学院，山西大同037009) 摘要：针对在Fe(OH) 胶体纯化过程中，难以在短时间内获得一定纯度的Fe(OH) 胶体的问题，探究了 3 3 两种Fe(OH) 胶体纯化的新方法，冷热交替渗析法和混合离子交换树脂法，并且对两种方法的最佳纯化 3 条件及其各自的优劣进行探索。实验结果表明：使用冷热交替渗析法，60 °C 热水浴渗析35 min 后冷水 浴渗析15 min，胶体的电导率可达560 μS ∙cm−1 ；而混合离子交换树脂法，当阴阳离子交换树脂的总质 量为10 g，且质量比为1 : 1，粗胶体的体积为45 mL 时，胶体的电导率可降至42 μS ∙cm−1 。两种方法 各有优劣，在教学实践过程中可根据实际情况灵活选择。 关键词：胶体；渗析；离子交换树脂；电导率 中图分类号：G64 ；O633 Two Novel Methods on Iron Hydroxide Colloid Purification GUAN Han-Chang DUAN Chang-Lin SHEN La-Zhen ZENG Lin-Xiang* (College of Chemistry Environmental Engineering, Datong University, Datong 037009, Shanxi Province, P. R. China) Abstract: In order to solve time-consuming problems during purification of coarse Fe(OH)3 colloid, two novel methods were proposed, that is, hot-cold alternating dialysis and mixed ion exchange resin. We investigated the optimum purification condition of the two methods. In addition, advantages and disadvantages were discussed in details. The results indicated that colloid conductivity could decrease to 560 μS ∙cm−1 when dealing with colloid in 60 °C hot water for 35 min and subsequently in cold water for 15 min. While using mixed anion