冶金渣制备生态型人工鱼礁混凝土试验探究.docVIP

冶金渣制备生态型人工鱼礁混凝土试验探究 　　摘要：通过正交试验研究了矿渣钢渣熟料石膏体系胶凝材料的强度。胶凝材料正交试验表明：矿渣：钢渣的复合比为7∶1，矿渣和钢渣的比表面积分别为480 m2·kg-1和550 m2·kg-1，并与10%的水泥熟料和10%的脱硫石膏复合的胶凝材料具有较高的强度。以优化后的胶凝材料代替水泥，并以热闷法稳定化的钢渣颗粒为骨料，可以制备出抗压强度达到65 MPa以上的人工鱼礁混凝土。利用XRD和SEM方法分析胶凝材料的水化过程，结果表明，水化反应主要生成AFt相和C-S-H凝胶，钢渣、水泥熟料和脱硫石膏的协同作用对矿渣的火山灰活性反应具有重要促进作用。 关键词：矿渣；钢渣；胶凝材料；混凝土；人工鱼礁 中图分类号：TU528.3 文献标志码：A 文章编号：1674-4764（2013）03-0145-06 A Primary Investigation on Concrete Made from Iron and Steel Slags for Building Ecological Artifical Reefs Ni Wen， Li Ying， Chen Deping， Wang Zhongjie （Civil and Environmental Engineering School； Key Laboratory of High-Efficient Mining and Safety of Metal Mines （Ministry of Education of China）， University of Science and Technology Beijing， Beijing 100083，P.R.China） Abstract： A method of orthogonal test was used to optimize the strength of the cementitious material for preparing the concrete of high-strength artifical reefs.The results show that with the ratio of iron slag：steel slag=7：1，and when 10% cement clinker and 10% gypsum of Flue Gas Desulfurization Waste （FGDW） was mixed with 80% iron and steel slags powder，the mixed cementitious material had an optimized strength.The optimized specific surface area are 480 m2/kg and 550 m2/kg for iron slag and steel slag powder respectively.The ordinary portland cement can be totally substituted by such a mixed cementitious material with iron and steel slags as its major components in preparing the concrete for building high-strength artificial reefs.A concrete with a compressive strengh over 65MPa can be prepared by using such a mixture as a cementitious material and steel slag grains as its fine and coarse aggregats which have been stubilized by a hot-simmering method. Hydration processes of net slurry were analysized by XRD and SEM methods. The results show that the hydration products in the system are mainly AFt and C-S-H gel. The results also show that the pozzolanic reaction of iron slags could be largely promoted by the