带有羧基的含氟丙烯酸酯共聚物的制备及超疏水性能研究Studyonthe.PDFVIP

2011 年第69 卷 化 学 学 报 Vol. 69, 2011 第12 期, 1425～1430 ACTA CHIMICA SINICA No. 12, 1425～1430 ·研究论文· 带有羧基的含氟丙烯酸酯共聚物的制备及超疏水性能研究 李晓艳 仇 伟 李欣欣* 韩哲文 (华东理工大学材料科学与工程学院 特种功能高分子材料及相关技术教育部重点实验室 上海 200237) 摘要 以甲基丙烯酸、甲基丙烯酸甲酯、甲基丙烯酸全氟烷基乙基酯为单体, 以可逆加成-断裂链转移方法合成含氟嵌 段共聚物, 同时以常规自由基溶液聚合制备相似组成的无规共聚物. 采用溶剂挥发成膜方法成膜, 研究共聚物组成与 结构对膜表面形貌和疏水性能的影响. 结果表明, 羧基单体的引入改变了含氟丙烯酸酯聚合物的溶解性能和成膜性能, 使用常用溶剂就可获得超疏水性膜. 当甲基丙烯酸甲酯、甲基丙烯酸物质的量的比在5 ∶1～1 ∶1 时, 聚合物疏水性能 最优; 研究甲苯、四氢呋喃、三氟甲苯三种不同溶剂对膜表面结构和疏水性质的影响, 其中甲苯所成膜的疏水性能最 优, 其疏水角高达157°. 嵌段共聚物因为链段规整, 疏水性较无规共聚物更好. 关键词 超疏水; 丙烯酸全氟烷基乙基酯; RAFT 聚合 Study on the Synthesis and Superhydrophobic Properties of Fluori- nated Copolymers with Carboxyl Group Li, Xiaoyan Qiu, Wei Li, Xinxin* Han, Zhewen (Key Laboratory of Specially Functional Polymeric Materials and Related Technology of the Ministry of Education, School of Materials Science and Engineering , East China University of Science and Technology, Shanghai 200237) Abstract The copolymers were synthetized by reversible addition-fragmentation chain transfer (RAFT) and free radical polymerization in cyclohexanone with monomers methyl methacrylate (MMA), methacrylic acid (MAA) and perfluoroalkyl ethyl methylacrylate (FMA). The surfaces were generated by one-step cast- ing process with different solvents. The surface morphologies and hydrophobicity of as-prepared films were determined by copolymer structure and composition. The carboxyl group could change the solubility of fluorinated copolymers and their