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（2009）Effect of nonionic surfactant molecular structure on cloud point extraction of phenol from wastewater.pdf

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Colloids and Surfaces A: Physicochem. Eng. Aspects 347 (2009) 200–209 Contents lists available at ScienceDirect Colloids and Surfaces A: Physicochemical and Engineering Aspects j o u rn al h omepage: w w w. elsev /locate/cols urfa Effect of nonionic surfactant molecular structure on cloud point extraction of phenol from wastewater Phanphat Taechangam a , John F. Scamehorn b,∗ , Somchai Osuwan a , Thirasak Rirksomboon a a The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, 10330, Thailand b Institute for Applied Surfactant Research, University of Oklahoma, Norman, OK 73019, USA a r t i c l e i n f o a b s t r a c t Article history: Above a temperature known as the cloud point, aqueous solutions of nonionic ethoxylated surfac- Received 4 August 2008 tants separate into two phases: a coacervate phase concentrated in surfactant and a dilute phase with Received in revised form 17 February 2009 low surfactant concentration. The coacervate phase contains surfactant aggregates which are micelles Accepted 1 April 2009 or micelle-like and will solubilize any organic solutes originally present in the water, resulting in a Available online 8 April 2009 liquid–liquid extraction known as a cloud point extraction (CPE). Removal of pollutants from water is an important potential application of CPE and we use phenol as a model organic pollutant in this work. In Ke