天然气中微量乙二醇取样测定.pdfVIP

学兔兔 石 油 与 天 然 气 化 工 第43卷 第6期 CHEMICAL ENGINEERING 0F 0IL 8L GAS 675 天然气中微量乙二醇的取样测定 韩 慧 王晓琴 分析计■与标准化 (1．中国石油西南油气田公司天然气研究院) (2．石油工业天然气质量监督检验中心) 摘 要 天然气采出后通过人工注入乙二醇作为水合物抑制剂，以预防设备和管道的堵塞。 建立可行有效的天然气中微量乙二醇取样测定方法，有利于对乙二醇加注量的指导。本方法采用 溶剂解吸型硅胶在管输压力下富集天然气中微量的乙二醇，再通过液体解吸后进行气相色谱分析。 在现场取样体积10 m。、用1O mL解吸液处理的条件下，乙二醇的检测限可达到0．05 mg／m。。 关键词 天然气 乙二醇 取样 气相色谱 分析 中图分类号：TE648 文献标志码：A DOI：10．3969／j．issn．1007—3426．2014．06．020 Sampling and determination of trace ethylene glycol in natural gas Han Hui ¨．Wang Xiaoqin ， (1．Research Institute of Natural gas Technology of PetroChina Southwest OilGasfield Company，Chengdu 610213，Sichuan，China；2．Natural Gas Quality Supervision and Inspection Center for Pertoleum Industry，Chengdu 610213，Sichuan，China) Abstract：Natural gas after produced is often served as a hydrate inhibitor by manual inj ection of ethylene glycol to prevent plugging of equipment and pipeline．The viable and effective method was established for sampling and determination of trace ethylene glycol in natural gas．It’S bene— ficial guidance to the inj ection amount of ethylene glyco1．The trace ethylene glycol in natural gas was enriched with the solvent desorption silica gel under pipeline pressure，and then desorption liquid was analyzed by gas chromatography after desorbing．The detection limits of ethylene gly— col can reach 0．05 mg／m。when the sample volume is 10 m。and the liquid used for desorption is 10 mL． Key words：natural gas，ethylene glycol，sampling，gas chromatography，analyze 天然气中的乙二醇主要为