2材料物理课件_（十二）.pptVIP

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2材料物理课件_（十二）.ppt

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2材料物理课件_（十二）

Polymer Solution 3 Questions What is polymer solution? Why to study polymer solution? HOW to study polymer solution? Key points for polymer dissolving Solvent selection (2) Similar solubility parameter Therefore ?HM is the key Hildebrand equation How to get ? ? (a) Swelling method： (b) Viscoelasticity method (c) Calculation Thermodynamical properties of the flexible chain polymer solutions However, the ideal solution is nonexistence 3.2.2 Thermodynamics of polymer solutions Flory-Hunggins Theory (Mean-field theory) Three Hypotheses 三点假设 Dissolving process （5） ?- state（ ?状态）（6）Discussion of Hunggins parameter Phase equilibrium of polymer solution What is the physical meaning of the second Virial coefficient A2? What we can get from the following equation? Discussion of A2 Discussion of the plot Stable, metastable and non-stable regions Different phase equilibrium diagrams Typical polymer-solution phase equilibrium diagram Molar volume of solvent Density of solute (2) A2 – Second Virial coefficient Intercept= Slope coefficient= Intercept slope (1) Number average molecular weight Mn ?? status 良溶剂劣溶剂 A2=0 A20 A20 Huggins parameter Status Second Virial coefficient (a) Add bad solvent into good solvent (b) Decrease temperature ? solvent ? temperature ?GM can be substituted by ?1 and Temperature Critical point Phase separation and dissolution are controlled by three variables: temperature, pressure, and concentration. LCST- Low critical solvency temperature UCST- Ultra critical solvency temperature Weak concentration High concentration Characteristic- Non-symmetry e.g. PVC raincoat, using plasticizer ?状态与理想状态之间的区别？ * * * * * * What is polymer solution? Why to study polymer solution? HOW to study polymer solution? Traditional Cover Study Best method on investigation of a single polymer Applictions Bond Dope Filature Plastic enhanced Blend Polymer solution process How to select a solvent Solution state：Interaction solution and separate Solution th