生物质热解和燃烧过程中钾的析出迁移特性研究.pdfVIP

编号：164349 生物质热解和燃烧过程中 钾的析出迁移特性研究 叶家铭，靳熹，杨金鑫，邓磊* ，车得福 (西安交通大学动力工程多相流国家重点实验室，西安 710049) 摘 要：生物质在热转化过程中，部分 K 进入到气相，会造成高温对流受热面积灰结渣和高温腐蚀等严重问题。本文利用固定 床实验系统对生物质热解和燃烧过程中碱金属的析出迁移特性展开了研究。实验结果表明：温度升高有助于小麦秸秆中 K 元素 的析出，而氧化性气氛能促进 K 元素的析出；小麦秸秆和稻壳的热解析出曲线差异较大，燃料种类对 K 元素的析出起着决定 性作用；在所研究的温度范围内，水溶性 K 的析出占据着主导地位。 关键词：生物质；碱金属；析出特性；热解；燃烧 中图分类号：TK16 文献标识码：A 1 Study on Release and Transformation of Potassium during Pyrolysis and v 0 Combustion of Biomass 7 YE Jia-Ming, JIN Xi, YANG Jin-Xin, DENG Lei*, CHE De-Fu 6 0 (State Key Laboratory of Multiphase Flow in Power Engineering, Xi’an Jiaotong University, Xi’an 710049) 0 Abstract: During the thermal conversion process of biomass, a fraction of K can release to the gas phase, causing . 1 serious problems of deposition and corrosion on high temperature convective heating surfaces. The release and 1 7 transformation of K during pyrolysis and combustion of biomass was studied in a fixed-bed experimental system. 1 The experimental results show that an increase in the temperature is beneficial to the release of K in wheat straw, 0 2 which will be facilitated in oxidizing atmosphere. There are great differences in the release of K during pyrolysis : between wheat straw and rice husk, which indicates that the fuel type plays a crucial role in the release of K. The v i release of water soluble K is dominant within the temperature range in this study. X a Keywords: biomass; al