采用真空薄带速凝工艺研制低钴贮氢合金研究.pdf

采用真空薄带速凝工艺研制低钴贮氢合金 张树雄 宋波毛碌红王福明 (北京科技大学) 结构和电化学特性。sEM分析表明：真空速凝薄片合金有细小的晶粒组成，成分均匀；而铸态合金的晶粒粗大，且 有明显的杂相析出。电化学测试表明：真空速凝合金活化性能好，最大放电容量(327mA．h／g)比铸态合金电极 的最大容量(309mA·h／g)有明显增大，真空速凝合金电极充放电循环稳定性优于铸态合金电极，具有较好的高倍 率充放电能力。利用真空薄带速凝工艺，可生产出高电化学稳定性的低钴AN型贮氢合金，合金的综合性能完全 达到实用化、产业化的要求，有望成为目前理想的贮氢合金制备方法。 关键词：真空薄带速凝。抵钴贮氢合金 电化学性能 onthe withLowCobaltContent Study HydrogenStorageAlloy Produced Method StripCasting by 130Mao ZhangShuxiongSong JinghongWangFuming ofScienceand (University TechnologyBeijing) Al葛tract：Inthis the and studyhydrogenstoragealloyML(NiCoMnAl)5．2(C03％一6％)waspreparedbystripcasting structureandelectrochemicalof was SEM melt—castingtechniquesrespectively．the performanceMloy investigated．The resultshowedthatthe SCmethodhasafine structureanduniform the analysis alloystripby grain composition，while hasa size and structure．Theelectrochemicalindicatedthatthe sC Mloy multi—phase casting largegrain analysis alloyby has activation maximum and with a better compared techniquegood property，higherdischargecapacity cyclingstability whichshoweda SC the with castingalloy goodhigh—ratecyclingcapability．UsingtechniquehydrogenstoragealloyAN lowCocontentand electrochemicalcanbe hi【gh stabilityproduced． withlowCocontentele