栲胶改性氨基磺酸系减水剂的工艺研究-生物质化学工程.pdfVIP

40 1 Vo.l 40 No. 1 2006 1 Biomass Chem ical Engineering Jan. 2006 栲胶改性氨基磺酸系减水剂的工艺研究 1 1 2 蒋新元 , 陈茜文, 万晓清 ( 1. 中南林学院工业学院, 湖南 长沙 410004; 2. 中南林学院 图书馆, 湖南 长沙 4 10004) : 利用栲胶部分取代苯 制改性氨基磺酸系减水剂, 研究了其改性工艺, 结果表明较佳改性的改性工艺条件为: 栲 胶占栲胶与苯 总质量的 25% ~ 37. 5% , 反应时间 3 h温度 0 pH 值 . 0~ 11. 0改性产物的分散性能较未改性 产物略有下降, 但 2 h流动度损失增大当掺入量为 0. 5% , 水灰比为 0. 28 1时, 掺改性产物和掺未改性产物的净浆流 动度分别为 240和 252mm : 栲胶; 苯 ; 氨基磺酸; 高效减水剂 : TQ 4 : A Study on Technology ofModified Am inosulfonic Acid-based Superplasticizer by V egetable Tannin JIANG X in-yuan, CHEN Q ian-w en, WAN X iao-q ing ( 1. College of Technology, Central South Forestry University, Changsha 4 10004, China; 2. Library, Cen tral South ForestryUn ivers ity, Changsha 4 10004, Ch ina) A bstrac t: In th is paper the m od ifying technology of vegetable tann in in p lace of phenol partially to produce am inosu lfon ic acid- based superp lasticizer was studied. The result ind icates that the better mod ified technological cond itions are as follow: m ass per- cent of vegetable tann in to total vegetab le tann in and phenol is betw een 25% - 37. 5% , reaction tmi e is about 3 h, tem perature is about 0 , and pH is betw een . 0 - 11. 0. The mod ified product has a little worse d ispersing capability than that of unmod ified product, bu t its slump loss is a little bigger. When the dosage in cem ent is 0. 5% , and the w ater-cement ratio is 0. 28 1, the flu id ity of cement paste added m od ified and unmod ified product is 240 and 252 mm, respectively. K ey w ord s: vegetable tann in; phenol; am inosu lfon ic acid; superplasticizer , , [ 1~ 3] 1 , 1. 1