菱镁矿石热分解特性和模型研究.docVIP

菱镁矿石热分解特性及模型研究 焦楷1，袁章福1，张利娜2，谢珊珊1，李林山3，隋殿鹏4 （1北京科技大学.钢铁共性技术协同创新中心，北京 100083； 2.冶金工业规划研究院，北京 100711； 3.大石桥市信威耐火材料有限公司，辽宁营口 115103； 4.东北大学 化学系，沈阳 110003） 摘要：以粒径900 μm的菱镁矿为原料，采用TG-DSC法研究了菱镁矿石热分解模型。结果表明菱镁矿的开始分解温度为800 K左右，950 K左右时分解完全，反应达到平衡。DSC曲线只有一个向下的峰与TG曲线失重台阶相对应，说明菱镁矿分解反应是一步反应，分解产生二氧化碳需要吸收热量。且随着升温速度的提高，菱镁矿需要在更高的温度下才能达到相同的分解程度。通过Flynn-Wall-Ozawa和Kissinger动力学分析方法计算菱镁矿热分解的平均活化能为260.54 kJ/mol，并利用Malek法分析菱镁矿热分解机理，菱镁矿分解为二维相边界反应，圆柱形对称模型，积分形式机理函数为G(α)=。 关键词：菱镁矿；TG-DSC；热分解动力学；机理函数TQ175.4 文献标志码：A 文章编号：1007-7545（2018）01-0000-00 Characteristic and Model of Thermal Decomposition of Magnesite JIAO Kai1a,1b, YUAN Zhang-fu1b, ZHANG Li-na2, XIE Shan-shan1b, LI Lin-shan3, SUI Dian-peng4 (a. Collaborative Innovation Center of Steel Technology, b. Institute of Engineering Technology, 1. University of Science and Technology Beijing, Beijing 100083, China; 2. China Metallurgical Industry Planning and Research Institute, Beijing 100711, China; 3. Dashiqiao Xinwei Refractory Materials Co. Ltd., Yingkou 115103, Liaoning, China; 4. Department of Chemistry, College of Science, Northeastern University, Shenyang 110003, China) Abstract：Thermal decomposition model of magnesite was investigated by TG-DSC analysis with magnesite (900 μm) as raw material. The result shows magnesite begins to decompose at about 800 K and completely decomposes at around 950 K. DSC curve shows one downward peak corresponding to weight loss process, indicating that decomposition reaction of magnesite is one-step and endothermic. With increase of heating rate, magnesite needs higher temperature to achieve the same degree of decomposition. Average activation energy of thermal decomposition of magnesite is 260.54 kJ/mol calculated by Flynn-Wall-Ozawa Method and Kissinger Method. Magnesite decomposition reaction model was discussed by Malek Method. Thermal decomposition reaction of magnesite is two-dimensional phase boundary reaction as cylindrical symmetric model. The kinetic equation of magnesite is G(α)=. Key word