固体进样－直接测汞仪法测定金精矿粉中微量汞.PDF

21 4 Vol. 21No. 4 56 2012 7 CHEMICAL ANALYSIS AND METERAGE July 2012 doi 10.3969j.issn.1008–6145.2012.04.017 130012 130062 n 900 0.28%~1.57% =6 1.0 gkg95.7 ~117.4 4 O657.99 A 1008–6145(2012)04–0056–03 Determination of Trace Mercury in Gold Concentrate Powder by Direct Mercury Analyzer with Solid Sampling Jia QingheYang Guangjun Metallurgical Research Institute of Jilin ProvinceChangchun130012China) Zhao QingsongChen Mingyan Hu Tingting, Xu LimingChen Zhen (Jilin Entry-Exit Inspection and Quarantine BureauChangchun130062China AbstractThe sample of gold concentrate powder was burned in the quartz boat with high pure oxygen and mercury released after Hg–Au being generated through the collecting tube. Mercury vapor released when the alloy was heated to 90 , then the mercury vapor was determined by atomic absorption spectrometry. The relative standard deviation of determination results was 0.28%–1.57%(n=6)and the detection limit was 1.0 gkg. The recovery was 95.7%–117.4%. Four soil standard samples were measured by this method, and the determination results were confi rmed with the standard values. The method is suitable for the determination of trace Hg in gold concentrate powder. Keywordsolid sampling; direct mercury analyzer; gold concentrate powder; mecury – 8–11 1 1.1 – (100150 ) (HG–AAS)(AFS)1–3 (ICP–MS) 900 4 – 253.65 nm