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Areviewofadsorbentsandadsorbatesinsolid–vapouradsorptionheatpumpsystems
A review of adsorbents and adsorbates in solid–vapour adsorption heat pump systems
N. C. Srivastava* and I. W. Eames
Institute of Building Technology, The University of Nottingham, University Park, Nottingham NG7 2RD UK
Received 3 November 1997.
Available online 22 November 1998.
Abstract
World-wide efforts to use solid–vapour adsorption technology for heat pumps have been intensified since the imposition of international restrictions on production and use of chlorofluorocarbons. Yet, to this date solid–vapour refrigeration and heat pump systems are still under laboratory testing stages. Promising recent developments in Japan, Europe and the U.S.A. include the use of porous metal hydrides and composite adsorbents. A review of adsorbents and adsorbates used in various investigations on solid–vapour adsorption heat pumps are presented in this paper, with an aim of initiating a novel concept experimental investigation.
Author Keywords:solid–vapour adsorption; heat pump; refrigeration; desiccant cooling
Article Outline
1. Introduction
2. Adsorption, adsorbents and adsorbates
2.1. Commercial hydrophilic solid adsorbents
2.1.1. Silica gel
2.1.2. Activated (or porous) alumina
2.1.3. Zeolites
2.1.4. Calcium chloride
2.2. Commercial hydrophobic solid adsorbents
2.2.1. Activated carbons
2.2.2. Metal oxides
2.2.3. Specially developed porous metal hydrides
2.2.4. Composite adsorbents
3. Adsorbents and adsorbates used in heat pump systems
3.1. Zeolite–water systems
3.2. Zeolite composites and water systems
3.3. Activated carbon–ammonia systems
3.4. CaCl2–methanol systems
3.5. Metal hydrides–hydrogen systems
3.6. Complex compounds/salts and ammonia or water
4. Conclusions
References
1. Introduction
Environment protection initiatives of international and national environment agencies have led to the intensification of research efforts on development of ozone and global warming safe heat pump technology. A number of older, but not fully exploited, technologies are being reassessed
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