季铵盐型双子表面活性剂在空气_水界面的单分子膜_英文_杨红伟.pdfVIP

23 2 原 子 与 分 子 物 理 学 报 Vol.23 No.2 2006 4 JOURNAL OF ATOMIC AND MOLECULAR PHYSICS Apr. 2006 # # : 1000 0364(2006) 02 0379 04 X XX 1 1 2 2 1 1 杨红伟, 朱谱新 , 冯玉军, 孙玉海 , 周栋梁, 吴大诚 (1. , 610065; 2. , 610041) : 利用Langmuir 膜天平测定不对称双子表面活性剂12 2 16 和对称双子表面活性剂12 2 12 在空气 水界面上 成单分子膜的表面压, 通过单分子膜的P-A 等温线微分等温线和静态弹性, 分析其相转变 和成膜特性. 结果表明, 与传统阳离子表面活性剂DTAB 比较, 12 2 1612 2 12 比 DTAB 单分子膜的分子 极限面积大, 崩溃压高, 并有较高的静态弹性, 因而具有较高的凝聚性和稳定性, 其中12 2 16 单分子膜的 凝聚性和稳定性最高. : 阳离子型双子表面活性剂; 单分子膜; 微分等温线; 静态弹性 : O647 : A Monol ayers f ormed from quaternary ammonium gemini surfactants at air-water i nterface 1 1 2 2 1 1 YANG Hong wei , ZHU Pu xin , FENG Yu jun , SUN Yu hai , ZHOU Dong liang , WU Da cheng ( 1. Textile Institute, Sichuan University, Chengdu 610065, P.R. China; 2. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, P. R. China) Abstract: Monolayers of a dissymmetric cationic quaternary ammonium gemini surfactant 12 2 16 and a sym metric gemini surfactant 12 2 12 were formed in KSV 2000 Langmuir trough at air water interface, respec tively. The surface pressure of each monolayer was measured using the Wilhelmy plate technique. The fea tures of monolayers at air water interface were discussed by analyzing the P-A isotherm, the differential curve and the static surface elasticity of monolayers for 12 2 12 and 12 2 16. It was found that such parameters as th