表面化学Surface_and_Interface_Chemistry教材教学课件.pptVIP

Surface and Interface Chemistry Contents Introduction Content of this course Technology for studying surface and interface The clean surface Surface structure The solid-gas interface Adsorption processes of gases on solids Surface reaction The solid-liquid interface Contact angles and wetting Ore flotation and detergency The liquid-gas and liquid-liquid interface Surface and interfacial tensions Adsorption and orientation at interfaces 1. Introduction 1.1 Surface and Interface Surface The interface between a substance and vacuum or gas Interface The point, area, or surface along which two substances or other qualitatively different things meet. Types of interface Gas-Liquid: G-L Liquid 1-Liquid 2: L1-L2 Gas-Solid: G-S Liquid-Solid: L-S Solid 1-Solid 2: S1-S2 Fluid interfaces Non-Fluid interfaces Notation: Less dense phase will be shown first Surface and interface chemistry is the study of chemical phenomena that occur at the interface of two phases. One important aspect of surface chemistry studies is to determine whether a molecule attaches itself to a surface by chemisorption or by physisorption. Interface chemistry mainly studies wetting, emulsification, dispersion, etc. phenomena. 1.2 Surface and interface chemistry 1.3 Importance of surface and interface Surface reactions Sensors Corrosion Heterogeneous catalysis Energy conversion Electronic device Pollution, Ozone hole Catalytic converters Interface reactions: Wetting, Emulsification, Dispersion, Penetration, etc. Textile industry Metallic industry Paint, Dyestuffs Agrochemicals Foodstuffs Cosmetics Paper Leather Detergent Plastic Techniques for studying surfaces Basic principle The analysis of surfaces rely on the micro particles-surface interaction to get the information of surfaces. Photons Electrons Ions Atoms Photons Electrons Ions Atoms Surface Common techniques (1) Auger Electron Spectroscopy (AES) Atomic Force Microscopy (AFM) Reflection Absorption Infra-Red Spectroscopy (RAIR