环保型有机硅改性聚醚密封胶的研制.pdfVIP

· · 114 黄活阳等，环保型有机硅改性聚醚密封胶的研制 Vol． 37，No． 2 ，2015 环保型有机硅改性聚醚密封胶的研制 黄活阳，何晓军，冯炬佳 （ 广东新展化工新材料有限公司，广东中山 528441） 摘要：以有机硅改性聚醚树脂、聚氧化丙烯二醇、填料、硅烷偶联剂和催化剂等原料，制备环保型单组份有机硅改性聚醚密 封胶，探讨其环保机理和力学性能。实验表明：以PPG3000为环保增塑剂，改性纳米碳酸钙为填料，当MS聚合物1和MS聚合 物2复配比例为80∶20时，密封胶的综合性能最佳；硅烷偶联剂和催化剂对密封胶的固化性能影响很大。 关键词：有机硅改性聚醚密封胶;单组份;环保 中图分类号：TQ436.6 文献标识码：A 文章编号：1001-0017（2015）02-0114-03 Development of Environmental Friendly Silicone Modified Polyether Sealant HUANG Huo-yang, HE Xiao-jun and FENG Ju-jia （Guangdong Xinzhan New Material Limited Company, Zhongshan 528441, China） Abstract: The environmental friendly type single component silicone modified polyether sealant was prepared with using silicone modified polyether resin, polypropylene oxide glycol, filler, silane coupling agent and catalyst. And its environmental friendly mechanism and mechanical prop － erties were explored. The experiments showed that when the PPG3000 was used as plasticizer and the modified nano calcium carbonate as filler, and the MS-polymer 1 and MS-polymer 2 blended with a ratio of 80 ∶20, the comprehensive properties of sealant would be optimal. The silane coupling a － gent and catalyst had a great influence on the curing properties of sealant. Key words: Silicone modified polyether sealant; single component; environmental friendly 室内装潢的单组份密封胶，环保无气味，施工性好， 前 言 不污染周边基材，而且具有优良的力学性能，对基 材的黏附性较好。 随着人们对室内装潢DIY要求和生活品味的 提高，室内装潢胶是否绿色环保越来越受到关注。 1 实验部分 传统的建筑用弹性密封胶诸如聚硫橡胶、聚氨酯密 封胶和有机硅酮胶有各自的缺陷，聚硫胶的耐久性 1.1 实验原料与仪器设备 和抗形变位移能力较差；而PU胶施工时会导致环 有机硅改性聚醚（MS聚合物1，MS聚合物2， 境污染，在湿气存在下易起泡；硅酮胶存在着污染