芳香族聚酰胺预聚体共聚改性聚己内酰胺的分析-analysis of polycaprolactam modified by copolymerization of aromatic polyamide prepolymer.docxVIP

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芳香族聚酰胺预聚体共聚改性聚己内酰胺的分析-analysis of polycaprolactam modified by copolymerization of aromatic polyamide prepolymer.docx

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芳香族聚酰胺预聚体共聚改性聚己内酰胺的分析-analysis of polycaprolactam modified by copolymerization of aromatic polyamide prepolymer

TheModificationofPolycaprolactamviaCopolymerizationwithAromaticPolyamidePrepolymerAbstractTheModificationofPolycaprolactamviaCopolymerizationwithAromaticPolyamidePrepolymerAbstractThepolyamide(PA)isonetypepolymerwithrepeatedamidelinkages,whichmostlyisusedtopreparesyntheticfiber.ForwearingyarnofPA,thefunctionalizationanddifferentiationhavebeenthemaintrendnowadays,coupledwiththewidespreadapplicationinapparelindustry,whichisregardedasasignaloffashioninasense.However,forPAindustrialyarn,industryconstantlytargettheimprovementofstrength,modulusandstabilityastheprimarygoalofRD.Presentresearchworkaimsattheindustrystatusofpolycaprolactam(PA6)industrialyarn,intheaspectofprincipleofmaterialdesign,anddevelopsahighstrengthPA6fiberwhichcouldbeproducedbygeneralmanufacturingtechnique.IncorporationwithoriginalrigidityofaromaticployamideandthesynergisticeffectofPA6chainfurtherimprovethemechanicalstrengthandotherpropertiesroundly.Meanwhile,themethodcanmeettheneedofgeneralsynthesisofPA6andmeltprocessing,whichmayshortenRDcycleandexpansetheapplicationfieldofPA6fiber.Thisstrategyfirstlydesignsandsynthesizesarigidaromaticpolyamideprepolymerwithactivatedend-groups,whichcouldbesolubleincaprolactam(CPL)melt.ThearomaticpolyamideprepolymercopolymerizeswithCPLinitsmelttoobtainAramid/polycaprolactamcopolymer(APA).Thecorrespondingdetailsandconclusionsasfollows:Aromaticpolyamideprepolymersweresynthesizedviaphosphorylationmethod,whosechainstructurewascharacterizedbyprotonnuclearmagneticresonance(1H-NMR),Ramanspectraandfouriertransforminfraredspectroscopy(FT-IR).Thecrystallizationstructure,chaintransitionbehaviorandsolubilityofaromaticpolyamideprepolymerswerealsoinvestigated.Withincreasethecontainofmeta-substitutedmoietyinmainchain,thearomaticpolyamideprepolymerscanbeeffectivelysolveinCPLmelt,whichisthepremiseofcopolymerizationofaromaticpolyamideprepolymersandCPL.AbstractTheModificationofPolycaprolactamviaCopolymerizationwithAromaticPolyamidePrepolymerAPAweresuccessfullysynthesizedviameltpolymerizati