改性TiO光催化剂的研究进展sy.docVIP

改性TiO2光催化剂的研究进展sy 导读：就爱阅读网友为您分享以下“改性TiO2光催化剂的研究进展sy”资讯，希望对您有所帮助，感谢您对92的支持! 改性TiO 2光催化剂的研究进展 内容摘要 本文对改性TiO 2的光催化反应机理及制备方法做了简要介绍，重点介绍了近年来国内外改性TiO 2在金属、非金属及共掺杂方面的研究进展。通过对TG 、XRD 、UV-vis 、XPS 、TEM 和光催化活性分析结果的对比，得出：掺杂能够有效控制光生电子-空穴的复合。当对TiO 2进行多种元素共掺杂，且掺入元素及量适当时，能使TiO 2的光催化性能进一步提高。研究表明：金属离子掺杂虽然在一定程度上提高了可见光的活性，但却降低了紫外光下的活性；而采用非金属掺杂不仅能够增强其可见光响应能力，且保持紫外区光催化活性。因此，金属与非金属元素共掺杂将是TiO 2光催化改性的重要方法。同时指出了TiO 2可见光催化存在的一些问题、发展前景及今后的研究方向。 【关键词】 TiO 2 掺杂 光催化活性 Progress in Research of Doping Modification of TiO2 Photocatalyst Abstract This article introduces recent progress of doping modification of TiO 2 photocatalyst doped with metal,non-metal and metal non-metal at home and abroad.The photocatalytic mechanism and preparation methods of nano-TiO 2 were brief described.The film surface was characterized by TG,XRD,UV-vis,XPS,TEM and the result of photocatalytic properties show that doping modification can produce lattice defects in TiO 2 by entering into the crystal lattices,thus the photocatalytic property of TiO 2 is improved by decreasing the electron-hole recombination.The results show that when two appropriate elements are chosen,and the doping concentrations and co-doping proportions are optimal, the photocatalytic properties of TiO 2 could be further enhanced.The photoactivity of the catalyst under UV light would be weakened with metal doped.Whereas with non-metal doped,not only the absorption band could be elongated to visible light,but also its activity under UV light be maintained.The non-metal ions doped was an important method to TiO 2 photocatalyst modification.While the prospect and problems of TiO 2 photocatalysis under the visible light are proposed. 【Key Words】TiO 2 doping photocatalytic properties 目 录 引言 ……………………………………………………………（1） 一、单元素掺杂 ………………………………………………（1） （一）金属元素掺杂 ……………………………………………（1） 1.稀土元素掺杂 ……………………………………………（1） 2. 过渡金属离子掺杂 …………………………………………（3） 3. 机理 ……………………………………………………（5） （二）非金属元素掺杂 …………………………………………（7） 1. 研究成果…………………………………